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We analyzed surface-wave propagation that takes place at the boundary between a semi-infinite dielectric and a multilayered metamaterial, the latter with indefinite permittivity and cut normally to the layers. Known hyperbolization of the dispersion curve is discussed within distinct spectral regimes, including the role of the surrounding material. Hybridization of surface waves enable tighter confinement near the interface in comparison with pure-TM surface-plasmon polaritons. We demonstrate that the effective-medium approach deviates severely in practical implementations. By using the finite-element method, we predict the existence of long-range oblique surface waves.
© 2013 Optical Society of America
1. Introduction
Artificial nanostructured materials can support electromagnetic modes that do not propagate in conventional media making them attractive for photonic devices with capabilities from nanoscale waveguiding to invisibility [1, 2]. The availability of metamaterials may lead to enhanced electromagnetic properties such as chirality, absorption, and anisotropy [3–5]. Engineered spatial dispersion is established as an essential route for diffraction management and subwavelength imaging [6, 7]. In particular, a giant birefringence also creates proper conditions for excitation of nonresonant hybrid surface waves with potential application in nanosensing [8, 9].
In its pioneering paper, Dyakonov theoretically demonstrated the existence of nondissipative surface waves at the boundary of a dielectric material and a transparent uniaxial medium [10]. However, the first experimental observation of Dyakonov surface waves came into sight more than 20 years later, most specially caused by a weak coupling with external sources [11, 12]. Indeed Dyakonov-like surface waves (DSWs) also emerge in the case that a biaxial crystal [13, 14] or a structurally chiral material [15, 16] takes the place of the uniaxial medium. The case of metal-dielectric (MD) multilayered media is specially convenient since small filling fractions of the metallic inclusions enable metamaterials with an enormous birefringence, thus enhancing density of DSWs and relaxing their prominent directivity [17–19]. We also include the relative ease of nanofabrication, bulk three-dimensional response, and broadband nonresonant tunability.
For near-infrared and visible wavelengths, nanolayered MD compounds behave like plasmonic crystals enabling a simplified description of the medium by using the long-wavelength approximation, which involves an homogenization of the structured metamaterial [20–22]. Under certain conditions, the second-rank tensor denoting permittivity in the medium include elements of opposite sign, leading to extremely anisotropic metamaterials [23, 24]. This class of nanostructured media with hyperbolic dispersion are promising metamaterials with a plethora of practical applications from biosensing to fluorescence engineering [25]. In this context, Jacob et al. showed for the first time the existence of DSWs when considering anisotropic media with indefinite permittivity [8]. This study was devoted mainly to surface waves enabling subdiffraction imaging in magnifying superlenses [26], where hyperbolic DSWs exist at the interface of a metal and an all-dielectric birefringent metamaterial. When considering hyperbolic media, however, the authors provided only an elusive analysis of DSWs.
In this paper we retake the task and we perform a thorough analysis of DSWs taking place in semi-infinite MD lattices showing hyperbolic dispersion. In the first part of our study, our approach puts emphasis on the effective-medium approximation (EMA). Under these conditions, different regimes are found and they are thoroughly analyzed. These regimes include DSWs with non-hyperbolic dispersion. Validation of our results is carried out when put into practice using numerical simulations based on the finite-element method (FEM). The major points of our interest are nonlocal effects caused by the finite size of the layers and dissipative effects due to ohmic losses in the metals. Finally, the main conclusions are outlined.
2. The hyperbolic regimes of the plasmonic crystal
The system under analysis is depicted in Fig. 1. An isotropic material of dielectric constant ε is set in the semi-space x > 0. Filling the complementary space, x < 0, we consider a periodic bilayered structure made of two materials alternatively stacked along the z axis. Specifically, a transparent material of dielectric constant εd and slab width wd is followed by a metallic layer, the latter characterized by the permittivity εm and the width wm. For simplicity, we assume that dielectric materials are nondispersive; indeed we set ε = 1 and εd = 2.25 in our numerical simulations. Furthermore, if a Drude metal is included, its permittivity may be written as
neglecting damping. Note that frequencies in Eq. (1) are expressed in units of the plasma frequency, Ω = ω/ωp.
Fig. 1 Schematic arrangement under study, consisting of a semi-infinite MD lattice (x < 0) and an isotropic material (x > 0). In the numerical simulations, the periodic structure includes a Drude metal and a dielectric with εd = 2.25.
Form anisotropy of this type of plasmonic devices may be modelled in a simple way by employing average estimates of the dyadic permittivity ε̿[27]. Under the conditions in which the EMA can be used (see details in Appendix A), the plasmonic lattice behaves like a uniaxial crystal whose optical axis is normal to the layers (the z axis in Fig. 1). The relative permittivity is set as ε̿ = ε⊥(xx+yy)+ε||zz. We point out that the engineered anisotropy of the 1D lattice is modulated by the filling factor of the metal, f, but also by its strong dispersive character [28].
In Fig. 2(a) we represent permittivities ε|| and ε⊥ of the plasmonic crystal shown in Fig. 1 for a wide range of frequencies. In practical terms, the filling factor of the metal governs the dissipative effects in the metamaterial, thus low values of f are of great convenience. Indeed f = 1/4 in our numerical simulations. For low frequencies, Ω ≪ 1, we come near the following expressions: ε⊥ ≈ fεm < 0 and 0 < ε|| ≈ εd/(1− f). Therefore, propagating TEz modes (Ez = 0) cannot exist in the bulk crystal since it behaves like a metal in these circumstances. On the other hand, TMz waves (Bz = 0) propagate following a spatial dispersion curve,
where spatial frequencies are normalized to the wavenumber kp = ωp/c. Note that Eq. (2) denotes an hyperboloid of one sheet (see Fig. 2(b) at Ω = 0.20). Furthermore, the hyperbolic dispersion exists up to a frequency for which ε⊥ = 0; in our numerical example it occurs at Ω1 = 0.359. For slightly higher frequencies, both ε|| and ε⊥ are positive and Eq. (2) becomes an ellipsoid of revolution; Figure 2(b) at Ω = 0.45 is associated with such a case. Since its minor semi-axis is , the periodic multilayer simulates an anisotropic medium with positive birefringence. Raising the frequency even more, ε|| diverges at leading to the so-called canalization regime [3]. For the plasmonic lattice in Fig. 1 it happens at Ω2 = 0.756. In general, Ω1 < Ω2 provided that f < 1/2. Beyond Ω2, Eq. (2) turns to an hyperboloidal shape. In the range Ω2 < Ω < 1, however, the dispersion curve has two sheets. Figure 2(b) illustrate this case at Ω = 0.80. Note that the upper limit of this hyperbolic band is determined by the condition ε|| = 0, or equivalently εm = 0, occurring at the plasma frequency. To conclude, ε⊥< (1 − f)εd in this spectral range.Fig. 2 (a) Variation of relative permittivities ε|| and ε⊥ as a function of normalized frequency Ω, for the plasmonic crystal of Fig. 1. Here we assume that f = 1/4. (b) Plot of Eq. (2) in the kykz plane for extraordinary waves (TMz modes) for the three different cases that we come across in the range Ω < 1. Solid line corresponds to kx = 0 and shaded regions are associated with harmonic waves with kx > 0 (non-evanescent fields).
3. Dyakonov-like surface waves
From an analytical point of view, our surface waves are localized at x = 0, their amplitudes decay as |x| → ∞, and ultimately they must satisfy Maxwell’s equations. For that purpose we follow Dyakonov by considering a modal treatment of our problem [10], also shown in Appendix B. This is a simplified procedure that is based on the characterization of the plasmonic lattice as a uniaxial crystal, enabling to establish the diffraction equation that gives the in-plane wave vector kD = [0, ky, kz] of the DSW.
In the isotropic medium, we consider a superposition of TEx (Ex = 0) and TMx (Bx = 0) space-harmonic waves whose wave vectors have the same real components ky and kz in the plane x = 0. These fields are evanescent in the isotropic medium, in direct proportion to exp(−κx), being the attenuation constant
in units of kp. On the other side of the boundary, the ordinary wave (o-wave) and extraordinary wave (e-wave) existing in the effective-uniaxial medium also decay exponentially with rates given by and respectively. Using the appropriate boundary conditions, Dyakonov derived the following equation [10] which provides the spectral map of wave vectors kD.In the special case of the surface wave propagation perpendicular to the optical axis (kz = 0), Eq. (8) reveals the following solution:
In the case: ε⊥ < 0 and ε < |ε⊥|, this equation has the well-known solution: which resembles the dispersion of conventional surface plasmon polaritons [29]. Indeed here we have purely TMx polarized waves, as expected. It is worth noting that no solutions in the form of surface waves can be found from the Eq. (8) in the case of propagation parallel to the optical axis (ky = 0) for hyperbolic metamaterials: ε⊥ε|| < 0. That means that there is a threshold value of ky for the existence of surface waves. However, for the frequencies and the filling factors when both ε⊥ < 0; ε|| < 0, the solutions of Eq. (8) appear in the form of Bloch surface waves [22], i.e. for ky = 0.4. DSWs in hyperbolic media
The analysis of DSWs takes into consideration effective-anisotropic metamaterials with indefinite permittivity, that is, provided that ε⊥ε|| < 0. In this case, DSWs may be found in different regimes, which depend not only on the elements of ε̿ characterizing the metamaterial, but also that of the surrounding isotropic material ε. Next we describe distinct configurations governing DSWs, first subject to a low value of the refractive index , namely ε < ε|| (ε < ε⊥) for low frequencies (in the neighborhood of the plasma frequency), and latter focused on a high index of refraction.
4.1. Low index of refraction n
First we analyze the case when ε < ε|| in the range Ω < Ω1, where in addition ε⊥ < 0 provided that f < 1/2. Note that this is satisfied if ε < εd/(1 − f). In the effective-uniaxial medium, o-waves are purely evanescent, and it is easy to see that κ < κo and also κe < κo. Under these circumstances, all brackets in Eq. (8) are positive provided that
By the way, even though Eq. (11) may be satisfied if −ε⊥ < ε, in this case we cannot find a stationary solution of Maxwell’s equations satisfying Dyakonov’s equation (8). This happens within the spectral band Ω0 < Ω < Ω1, where Note that Ω0 = 0.292 in our numerical simulation. For instance, in the limiting case ε = −ε⊥, the unique solution of Eq. (8) is found for ky → ∞ and kz = 0, as can be deduced straightforwardly from Eq. (10).In Fig. 3(a) and (b) we illustrate the dispersion equation of DSWs for two different frequencies in the range 0 < Ω < Ω0. In these cases, DSW dispersion curve approaches a hyperbola. Contrarily to what is shown in Fig. 3(b), we find a bandgap around kz = 0 in (a). In general terms it occurs if Ω < 0.271, whose limiting frequency is determined by the condition
In this sense we point out that hybrid solutions near kz = 0 are additionally constrained to the condition [see also Eq. (10)], which is a necessary condition for κe to exhibit real and positive values. Finally, a case similar to that shown in Fig. 3(b) was first reported in Fig. 5(b) from Ref. [8], though some discrepancies are evident.Fig. 3 Graphical representation of Eq. (8), drawn in solid line, providing spatial dispersion of DSWs arising in the arrangement of Fig. 1, at different frequencies: (a) Ω = 0.20, (b) Ω = 0.28, and (c) Ω = 0.85. Here, the metamaterial is characterized by f = 0.25 and the isotropic medium is air. As a reference we also include equations κ = 0 (dotted line) and κe = 0 (dashed line). (d) Dispersion equation for DSWs as given in (c) but ranged over the region of interest. Points A, B, C, and SP are used in Fig. 4.
In order to determine the asymptotes of the hyperbolic-like DSW dispersion curve, we consider the quasi-static regime (Ω → 0) since |kD| = kD ≫ Ω. Under this approximation, κ = kD, κo = kD, and κe = ΘkD, where
being ky = kD cosθ, and kz = kD sinθ. Note that 0 ≤ Θ ≤ 1. By inserting all these approximations into Eq. (8), and performing the limit kD → ∞, we attain the equation ε + ε⊥Θ = 0 straighforwardly. The latter equation indicates that hyperbolic-like solutions of Dyakonov’s equation may be found provided that ε⊥ < 0 and additionally ε < −ε⊥, occurring in the range Ω < Ω0. In this case, the asymptotes follow the equation kz = ky tanθD, where These asymptotes establish a canalization regime leading to a collective directional propagation of DSW beams [8, 9, 28]. At this point it is necessary to remind that the asymptotes of the e-waves dispersion curve, in the kykz-plane, have slopes given by tan2 θe = −ε⊥/ε||. As a consequence θD < θe, as illustrated in Fig. 3(b), and in the limit Ω → 0 (ε⊥ → −∞) we obtain θD→θe.Moving into the high-frequency band Ω2 < Ω < 1, we now find that ε|| < 0 < ε⊥. The plot shown in Fig. 3(c) corresponds to this case. In a similar way found in Fig. 3(a) and (b), note the relevant proximity of DSW dispersion curve to κe = 0. Opposedly it crosses the e-wave hyperbolic curve at two different points, where solutions of Dyakonov’s equation begin and end respectively. In comparison, the angular range of DSWs turns to be significantly low. Apparently the z-component of kD tends to approach caused by the simultaneous dominance of o- and e-waves. In general, an slight increase of the refractive index in the isotropic medium pushes the wave vector kD to higher values, leading to an enormous shortening in the dispersion curve of the surface waves. As a consequence, high-n materials give rise to adverse conditions for the excitation of DSWs in the neighborhood of the plasma frequency.
Figure 4 shows the magnetic field for the points A, B, and C, all highlighted in Fig. 3. Also we represent the z-component of the field B that is associated with the point SP appearing in Fig. 3(b), and that corresponds to a surface plasmon (Bx = 0). The wave field is tightly confined near the surface x = 0, in a few units of 1/kp, for the cases A and B. Such a wave localization is even stronger than the confinement of the surface plasmon appearing at Ω = 0.28 (at ky = 0.625). This is caused by the large in-plane wavenumber of the DSW, being kD = 1.44 and 1.03 for the points A and B, respectively. Exceptionally, the lowest confinement is produced at Ω = 0.85 when making the choice C, in spite of considering a DSW with large wave vector kD = [0, 0.2, 1.07]. In this case, the interplay of slowly-decaying o- and e-waves counts against localization of the surface wave.
Fig. 4 Variation of the magnetic field (a) |Bx| and (b) |Bz| along the x-axis for the points A, B, and C highlighted in Fig. 3. The field is normalized to unity at its maximum absolute value. We include the point SP associated with TMx surface waves.
Fig. 5 (a) Solutions of Eq. (8) at a frequency Ω = 0.10 for an isotropic medium of permittivity ε = 10 and a layered metamaterial composed of a Drude metal and a dielectric of εd = 2.25. Curves κ = 0 and κe = 0 are also drawn in dotted and dashed lines, respectively. Profile of the magnetic field (b) |Bx| and (c) |Bz| along the x-axis for the point D shown in (a), including the point SP associated with a TMx surface wave.
4.2. High index of refraction n
Next we analyze the case when ε|| < ε in the spectral domain Ω < Ω1. Therefore, the curve κ = 0 characterizing the isotropic medium crosses the TMz dispersion curve κe = 0 of the uniaxial metamaterial. Note that such a curve crossing is mandatory by considering materials with all-positive permittivities, alike the pioneer paper by Dyakonov [10, 13]. Our current case discloses some similarities with DSWs analyzed in Sec. 4.1. For instance, no solutions of Dyakonov’s equation (8) are found if additionally −ε⊥ < ε, occurring at Ω0 < Ω < Ω1. Nevertheless, there are some distinct features which are worthy to mention.
In our numerical simulations we used a dielectric material with ε = 10, leading to Ω0 = 0.145. In Fig. 5(a) we illustrate the dispersion equation of DSWs at Ω = 0.1. Here DSW curve also approaches a hyperbola. In our instance, however, on-axis bandgaps are not found even at lower frequencies, and Eq. (8) provides solutions for every real value of kz. Figs. 5(b) and 5(c) show the profile of the magnetic field along the x axis for two different points (D and SP) of the dispersion curve. Once again, hybrid surface waves (case D) exhibit a tighter confinement near the boundary x = 0 than that offered by the solution of Eq. (8) and that is attributed to surface plasmons with pure TMx polarization (case SP).
Finally by assuming ε⊥ < ε at a given frequency of the spectral window Ω2 < Ω < 1, we have not found solutions of Eq. (8). As discussed in Sec. 4.1, high values of ε goes in prejudice of the appearance of hybrid surface waves.
5. Validity of the effective-medium approximation
In the previous sections we have utilized EMA to represent MD multilayered metamaterial as a uniaxial plasmonic crystal. However, it was shown recently that EMA does not describe properly neither nonlocalities (even in the case of negligible losses) [31], nor it takes into account correctly metallic losses [32]. In fact, the MD layered nanostructure demonstrates strong optical nonlocality due to excitation of surface plasmon polaritons, depending on the thicknesses of the layers. Dispersion and diffraction properties of the periodic nanolayered metamaterial can be dramatically affected by strong coupling among surface plasmon polaritons excited at metal-dielectric interfaces. In many cases, EMA produce results that are so different from the exact transfer-matrix method [27] that cannot be taken into account as small corrections [30]. In particular, the existence of additional extraordinary wave has been revealed [31] which enable double refraction of TMz-polarized beam into negatively and positively refracted parts, within the favourable frequency range. Here, however, we deal with hyperbolic metamaterials that require frequency ranges out of the double refraction range. Confining ourselves to the wave fields of TMz polarization which approach e-wave in the regime of validity of EMA, the exact map of wave vectors kD characterizing Bloch waves is calculated via:
where φq = kqzwq, and is the dispersion equation for bulk waves inside the dielectric (q = d) and Drude metal (q = m).Equation (16) is graphically represented in Fig. 6 for the MD crystal displayed in Fig. 1 at x < 0, considering different widths wm of the metal but maintaining its filling factor, f = 0.25; ohmic losses in the metal are neglected once again. We use the same configurations appearing in Figs. 3(a)–3(c) and Fig. 5(a). In the numerical simulations, we set kx = 0 in Eq. (16) accordingly. We observe that the EMA is extremely accurate for wm = 0.1 (in units of 1/kp) in the region of interest. However, deviations among the contours are evident for wider metallic layers. Apparently, Eq. (16) is in good agreement with the EMA in the vicinity of kz = 0, but rising wm makes the dispersion curve to sheer in direction to the z axis. As a general rule, given a value of the on-axis frequency kz, Eq. (16) yields lower values of ky. As shown in the next section, this is also the cause of a spectral shift of kD along the same direction.
Fig. 6 Exact dispersion curves of TMz modes in a Drude-metal/dielectric compound for different widths of the metallic layer, starting from wm → 0 (dashed line) and including higher widths at a constant rate of 1/10kp (solid lines). For an isotropic medium of permittivity ε = 1, frequencies are: (a) Ω = 0.20, (b) Ω = 0.28, and (c) Ω = 0.85. For ε = 10 we represent TMz modal curves at (d) Ω = 0.10. Also the curve κ = 0 is included in dotted lines.
The Bloch waves involved in the formation of the DSW and caused by nonlocality in the structured medium have an impact on the wave vector kD at the interface x = 0, as seen above, but also put additional conditions on this boundary. Since the introduction of an effective permittivity requires some kind of field averaging normally to the metal-dielectric layers, the excitation of evanescent fields in the isotropic medium would be fundamentally governed by the value of kD which determines the attenuation constant κ given in Eq. (5). However, spatial dispersion also leads to strong field oscillations across the system [30–32]. This means that the conventional boundary conditions imposed by the equation det(M̿) = 0 are not valid anymore. Such a strong variation of the field is set on the scale of a single layer. Consequently, evanescent fields with spatial frequencies much higher than kD will participate vigorously in the isotropic medium extremely near the boundary. As we will see in the FEM simulations appearing in the next section, predominance of these high-frequency components of the field lies crucially by the edge of the metallic layers adjoining the isotropic medium.
6. Analysis of a practical case
Dissipation in metallic elements is a relevant issue of plasmonic devices. Taking into account ohmic losses, permittivities in Eqs. (1)–(18) become complex valued. Consequently Dyakonov’s equation (8) provides complex values of the wave vector kD. This procedure has been discussed recently by Vuković et al in [18]. Nevertheless, practical implementations are out of the long-wavelength limit, thus we also direct our efforts toward nonlocal effects. Numerical techniques to solve Maxwell’s equations seem to be convenient tools in order to provide a conclusive characterization of DSWs at the boundary of realistic metallodielectric lattices.
In order to tackle this problem, we evaluate numerically the value of ky for a given Bloch wavenumber kz. Since the imaginary part of εm is not neglected anymore, ky becomes complex. This means that the DSW cannot propagate indefinitely; Im(kx) denotes the attenuation factor of the surface wave along the metallic-film edges. In our numerical simulations we consider a dissipative DSW propagating on the side of a Ag-PMMA lattice at a wavelength of λ = 560 nm (normalized frequency Ω = 0.28), where the surrounding isotropic medium is air. Accordingly ε = 1, εd = 2.25, and εm = −11.7 + 0.83i (being Ωp = 12.0 rad/fs) [33]. Bearing in mind a practical setting in the plasmonic lattice with current nanotechnology, we apply wm = 9 nm and f = 0.25.
Our computational approach lies on the FEM by means of COMSOL Multiphysics software. Thus given kz = 0.25, which is associated with the point B in Fig. 3(b), we finally estimate the complex propagation constant: ky = 0.70 + 0.06i. We point out that Eq. (8) predicts a value ky = 0.85 + 0.24i; in addition we obtain ky = 1.00 by neglecting losses in Dyakonov’s equation, as shown in Fig. 3(b). Our numerical experiment proves a “red shift” in the propagation constant caused by nonlocal effects. Furthermore, Im(kx) decreases sharply (roughly by a ratio 1/4) in comparison with EMA estimates. This major result enable DSWs propagating along distances significantly longer than those predicted by the long-wavelength approach.
Figure 7 shows the magnetic field B of the DSW in the xz-plane. The calculated pattern in one cell reveals the effects of retardation clearly. Along the z axis, an abrupt variation of B is evident inside the nanostructured material, in contrast with assumptions involving the effective-medium approach. The wave field cannot penetrate in the metal completely, and it is confined not only on the silver-air interface but also in the Ag-PMMA boundaries near x = 0. Indeed, from FEM simulations, the ratio of max|Bx| over max|Bz| yields 0.80, considerably higher that its value on the basis of the EMA (equal to 0.37). This proves a field enhancement on the walls of the metallic films and inside the dielectric nanolayers, minimizing dissipative effects in the lossy metamaterial. Finally, the distributed field along the x axis is analogous in all cases, also by comparing with EMA-based results.
Fig. 7 Contour plots of the magnetic fields (a) |Bx| and (b) |Bz| in the xz-plane, computed using FEM. The hyperbolic metamaterial is set on the left, for which only one period is represented. Also we graph the fields along (1) the center of the dielectric layer, (2) the center of the metallic slab, and (3) a plane containing the Ag-PMMA interface.
7. Conclusions
We showed that excitation of DSWs at the boundary of an isotropic dielectric and a hyperbolic metamaterial enable distinct regimes of propagation. At low frequencies, DSWs exhibit the well-known hyperbolic-like dispersion [8]. Exclusively, this occurs provided that 0 < ε < −ε⊥. Importantly its vertex is placed on the ky axis, coinciding with a non-hybrid TMx surface wave. If is satisfied, a bandgap around kz = 0 arises in the DSW dispersion curve. However, these bandgaps disabling negative refraction would disappear by using an isotropic material with a sufficiently-high index of refraction, n.
Conversely, severe restrictions are found at high frequencies where ε|| < 0 < ε⊥ (two-sheet hyperboloidal dispersion). DSWs dispersion curve crosses the e-wave hyperbolic curve at two different points, where solutions of Dyakonov’s equation begin and end. In comparison with the previous case, the spectral range of DSWs turns to be significantly low. Furthermore, high-n materials give rise to adverse conditions for the excitation of DSWs.
We point out that the wave field of DSWs keeps tightly confined near the surface x = 0. Such a wave localization is even stronger than the confinement of the (TMx) surface plasmon appearing at kz = 0.
In the last part of this paper we analyzed retardation effects and dissipation effects caused by the finite width and ohmic losses of the metallic nanolayers, respectively. As a practical implementation we considered a dissipative DSW propagating at the boundary of an Ag-PMMA lattice and air. Our FEM-based numerical experiment proves a “red shift” in the propagation constant caused by nonlocal effects. Furthermore, the field is enhanced on the walls of the metallic films and inside the dielectric nanolayers, minimising dissipative effects in the lossy metamaterial. As a consequence, DSWs propagate along distances significantly longer than those predicted by the long-wavelength approach.
Finally, let us point out that the properties of the resulting bound states change rapidly with the refractive index of the surrounding medium, suggesting potential applications in chemical and biological sensing and nanoimaging.
Appendix A: Effective-medium approximation
The EMA involves a material homogenization, a procedure that requires the metallic elements to had a size of a few nanometers. This is caused by the fact that transparency of noble metals is restrained to a propagation distance not surpassing the metal skin depth, LD[22, 30, 34, 35]. In the Drude approach, LD may be roughly estimated by the inverse of kp, that is deeply subwavelength in practice. In reference to this point, recent development of microfabrication technology makes it possible to create such subwavelength structures [36, 37]. Under these conditions, the plasmonic lattice behaves like a uniaxial crystal characterized by a relative permittivity tensor ε̿ = ε⊥ (xx + yy) +ε||zz, where
gives the permittivity along the optical axis, and corresponds to the permittivity in the transversal direction. In the previous equations, denotes the filling factor of the metal.Appendix B: Derivation of the Dyakonov’s equation
This appendix shows the procedure to derive the dispersion equation for the wave vector kD of the DSW. We start with the analytical expressions of the electric and magnetic fields involved in the boundary problem. In the isotropic medium, the bimodal electric field may be written in the complete form as E(r,t) = E(x) f (y,z,t), where
and in x > 0. Here time- and space-coordinates are normalized to the inverse of ωp and kp, respectively. In addition ATE and ATM are complex-valued amplitudes, and the vectors Note that the polarization vector a1 lies on the plane x = 0 where the DSW propagates, but it is perpendicular to its direction of propagation, kD. For the magnetic field we apply the Faraday’s law of induction, iΩcB = ∇ × E. In this case B(r,t) = B(x) f (y,z,t), where From Eqs. (21) and (24) it is clear that ATE and ATM represent amplitudes of the TEx and TMx modes, respectively.On the other side of the boundary, the dependence along the x direction of the multimodal electric field in x < 0 may be written as
Here Ao and Ae stand for the amplitudes of the o-wave and the e-wave, respectively. Also we define the vectors Note that the vectors bo,e are perpendicular to the optical axis. The part of the magnetic field which provides its variation normally to the isotropic-uniaxial interface is set now as As it is well-known, Eqs. (25) and (28) verify that the o-wave corresponds to a TEz mode and the e-wave is associated with a TMz mode.Next we apply the standard electromagnetic-field boundary conditions at x = 0, that is, continuity of the y- and z-components of the fields E and B at the planar interface. This problem may be set in matrix form as
where the vector A = [ATE, ATM, Ao, Ae] includes the amplitudes of the four modes that the DSW integrates. In addition, the 4 × 4 matrix Nontrivial solution of Eq. (29) may be found if the determinant of M̿ vanishes. In this way, Dyakonov derived equation (8), which provides the spectral map of wave vectors kD.Acknowledgments
This research was funded by the Spanish Ministry of Economy and Competitiveness under the project TEC2011-29120-C05-01, by the Serbian Ministry of Education and Science under the project III 45016, and by the Qatar National Research Fund under the project NPRP 09-462-1-074. CJZR gratefully acknowledges a financial support from the Generalitat Valenciana (grant BEST/2012/060).
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