Table 1
Observed Wavelengths (in Angstroms) for 3p 6 3d 8 –3p 5 3d 9 Transitions in Ru18+ , Rh19+ , Pd20+ , Ag21+ , and Cd22+
Transition 3p 6 3d 8 –3p 5 3d 9 Ru18+ Rh19+ Pd20+ Ag21+ Cd22+
gAa Intb λ Int λ Int λ Int λ Int λ [3, 5]4 –(3/2, 5/2)4 3 2 78.214 3 75.310 15 72.630 15 70.130 5 67.781 [2, 6]2 –(3/2, 5/2)2 13 40w 76.900 30 74.170 35 71.655 20 69.334 40 67.170 [3, 5]1 –(3/2, 5/2)2 6 5 76.176 25 73.336 15 70.711 15 68.258 25p 65.957 [2, 6]0 –(3/2, 3/2)1 7 3w 75.989 2w 73.186 15 70.599 5 68.195 20u 65.948 [3, 5]2 –(3/2, 5/2)2 11 50 74.960 10 72.169 [2, 6]2 –(3/2, 5/2)3 10 120 74.875c 10 72.139 8 69.618 20 67.289 20 65.120 [3, 5]4 –(3/2, 5/2)3 10 120 74.875c 15 71.988 10u 69.296 10 66.819 25 64.487 [3, 5]3 –(3/2, 5/2)4 10 60 74.568 20 71.822 10u 69.282 40 66.907 35 64.681 [3, 5]3 –(3/2, 5/2)3 35 10u 66.248 [3, 5]3 –(3/2, 5/2)2 2 10w 73.372 15 70.631 [4, 4]2 –(3/2, 5/2)2 120 800 73.320 600 70.452 2000 67.777c 1400 65.266 1200 62.906 [3, 5]2 –(3/2, 5/2)3 2 5 73.038 3 67.663 [2, 6]2 –(3/2, 3/2)2 36 80 72.970 90 70.273 2000 67.777c 70 65.441 50 63.261 [4, 4]4 –(3/2, 5/2)4 152 1500 72.826 1500 69.989 1500 67.344 1500 64.864 1500 62.540 [3, 5]1 –(3/2, 5/2)1 37 80p 71.840 80 69.102 100 66.554 100 64.171 60 61.946 [4, 4]0 –(3/2, 5/2)1 29 40 71.616 15 68.808 50 66.191 100 63.726 50 61.418 [4, 4]2 –(3/2, 5/2)3 8 150 71.483c 2w 63.448 10 61.108 [3, 5]1 –(3/2, 3/2)0 43 150 71.483c 25 68.700 70 66.108 150 63.670 70 61.387 [3, 5]4 –(3/2, 3/2)3 58 300 71.356 200 68.548 120 65.928c 600 63.483 400 61.185 [3, 5]2 –(3/2, 3/2)2 48 60 71.224 100 68.476 120 65.928c 300 63.521 65 61.273 [3, 5]2 –(3/2, 5/2)1 63 900 70.765 200 68.065 100 65.561 400 63.222 70 61.039 [4, 4]4 –(3/2, 5/2)3 174 2000 69.929 2000 67.104 1500 64.477 1500 62.021 2000 59.723 [3, 5]3 –(3/2, 3/2)2 164 1200 69.791 2000 67.098 800 64.575 1200 62.216 1300 60.005 [4, 4]2 –(3/2, 3/2)2 10 5 69.750c 2 64.298 65 59.464 [3, 5]1 –(3/2, 3/2)1 4 5 69.750c [4, 4]0 –(3/2, 3/2)1 23 3u 59.679 [3, 5]2 –(3/2, 3/2)3 39 100 69.693 50 66.971 5 64.447 70 62.082 10 59.860 [4, 4]2 –(3/2, 5/2)1 4 30u 61.530 120 59.246 [3, 5]2 –(3/2, 3/2)1 31 90 68.723 35 66.115 70 63.700 350 61.440 100 59.323 [3, 5]3 –(3/2, 3/2)3 104 500 68.319 200 65.641 250 63.158 600 60.833 900 58.648 [4, 4]2 –(3/2,3/2)3 3 30 65.479 1 62.892 [4,4]2 –(3/2, 3/2)1 137 600 67.342 150 64.667 250 62.179 600 59.837 800 57.628 [4, 4]4 –(3/2, 3/2)3 254 1100 66.857 350 64.103 300 61.546 1000 59.141 1100 56.883 [2, 6]2 –(1/2, 3/2)2 135 100 66.228 150 63.124 200 60.234 600 57.514 500 54.952 [2,6]0 –(1/2,3/2)1 55 40 65.402 20 62.374 5 59.544 30 56.876 15 54.358 [2, 6]2 –(1/2, 5/2)2 21 15 65.270 10 57.111 [3, 5]2 –(1/2, 3/2)2 23 8p 64.785 15 61.674 2 58.763 10 56.028 30p 53.448 [3, 5]1 –(1/2, 3/2)2 0 [3, 5]1 –(1/2, 5/2)2 100 80 64.750 40 61.772 70 58.991 100 56.373 100 53.900 [3, 5]2 –(1/2, 5/2)2 78 60 63.870 100w 60.933 60 58.208 200 55.638 120 53.209 [4, 4]2 –(1/2, 3/2)2 15 3 63.557 1 60.414 20 52.072 [3, 5]3 –(1/2, 5/2)2 150 80 62.711 100 59.839 150 57.156 250 54.633 52.251d [3, 5]3 –(1/2, 3/2)2 3 [4, 4]2 –(1/2, 5/2)2 13 5w 62.669 [3, 5]4 –(1/2, 5/2)3 710 1100 62.338 600 59.596 700 57.024 1200 54.596 1500 52.292 [3, 5]2 –(1/2, 5/2)3 5 2 55.905 2w 53.548 2 51.322 [2, 6]2 –(1/2, 3/2)1 140 80 61.177 50 58.409 60 55.820 250 53.384 100 51.078 [4, 4]0 –(1/2,3/2)1 8 1 52.437 [3, 5]3 –(1/2, 5/2)3 39 12 59.999 20 57.388 20 54.938 35 52.619 20 50.428 [3, 5]2 –(1/2,, 3/2)1 42 10 59.944 10 57.161 5 54.558 10 52.096 1 49.771 [4, 4]4 –(1/2, 5/2)3 6 3 51.353
a Calculated transition probabilities in 10
10 (sec
−1 ) for Ru
18+ .
b Symbols: p, perturbed by close line; u, unresolved shoulder; w, wide.
c Doubly classified.
d Blended with line of Cu-like ion.
Table 2
Observed Wavelengths (in Angstroms) for 3p 6 3d 8 –3p 5 3d 9 Transitions in In23+ , Sn24+ , Sb25+ , Ba30+ , and La31+
Transition 3p 6 3d 8 –3p 5 3d 9 In23+ Sn24+ Sb25+ Ba30+ La31+
gAa Intb λ Int λ Int λ Int λ Int λ [3, 5]4 –(3/2, 5/2)4 6 15 65.590 125w 63.528 [2, 6]2 –(3/2, 5/2)2 10 12 65.162 3 63.291 [3, 5]1 –(3/2, 5/2)2 9 25w 63.814 75 61.801 [2, 6]0 –(3/2, 3/2)1 9 30 61.884 [3, 5]3 –(3/2, 5/2)4 12 10 62.607 15w 60.649 [3, 5]4 –(3/2, 5/2)3 9 6 62.320 [2, 6]2 –(3/2, 3/2)2 35 150 61.228 100 59.317 [4, 4]2 –(3/2, 5/2)2 177 1500 60.689 1500 58.596 50 56.626 3 48.147 5u 46.690 [4, 4]4 –(3/2,5/2)4 187 1500 60.352 1500 58.290 50 56.347 4 47.990 5 46.557 [3, 5]1 –(3/2, 5/2)1 40 150 59.867 75 57.920 [3, 5]3 –(3/2, 5/2)3 17 50 59.614 30 57.679 [4, 4]0 –(3/2, 5/2)1 46 300 59.245c 50 57.204 [3, 5]1 –(3/2, 3/2)0 54 300 59.245c 50 57.219 [3, 5]2 –(3/2, 3/2)2 54 250 59.164 60 57.171 30w 55.301 2 47.204 [3, 5]4 –(3/2, 3/2)3 134 600 59.032 300 57.002 30 55.090 3 46.904 8 45.506 [3, 5]2 –(3/2, 5/2)1 47 250 59.000 75 57.089 [4,4]2 –(3/2, 5/2)3 15 100 58.912 10 56.836 3 46.574c [3, 5]1 –(3/2, 3/2)1 12 25 56.244 3 46.574c [3, 5]3 –(3/2, 3/2)2 222 1200 57.927 350 55.967 50 54.122 5 46.173 4 44.804 [4,4]4 –(3/2,5/2)3 328 1350 57.571 55.553d 30 53.643 30 45.523 10 44.139 [4,4]2 –(3/2, 3/2)2 15 30 55.165 [3, 5]2 –(3/2, 3/2)3 32 5 55.821 [3, 5]2 –(3/2, 3/2)1 94 300 55.455 53.683d 4 46.008 44.671e [4, 4]2 –(3/2, 5/2)1 35 120 57.110 40 55.092 3 45.137 10 43.758c [3, 5]3 –(3/2, 3/2)3 140 300 56.605 250 54.676 30 52.869 3 45.083 10 43.758c [4,4]2 –(3/2, 3/2)1 112 250 55.546 300 53.577 5 51.709 [4,4]4 –(3/2, 3/2)3 210 300 54.756 300 52.757 7 50.861 4 42.684 [2,6]2 –(1/2, 3/2)2 216 275 52.550 60 50.260 10 48.118 [2, 6]2 –(1/2, 5/2)2 8 30 50.340 [2, 6]0 –(1/2, 3/2)1 79 60 51.986 49.736e [3,5]1 –(1/2, 5/2)2 139 125 51.572 50 49.392 5 47.306 2 38.324 3 36.750 [3, 5]1 –(1/2, 3/2)2 2 50p 49.323 [3, 5]2 –(1/2, 5/2)2 154 250 50.928 30 48.786 3 46.737 37.928f 5 36.369 [3, 5]2 –(1/2, 3/2)2 6 30 48.713 [3, 5]4 –(1/2, 5/2)3 867 1800 50.119 600 48.057 60 46.100 15 37.549 10 36.051 [3, 5]3 –(1/2, 5/2)2 196 275 50.006 60 47.912 5 45.901 37.258d 35.746d [3, 5]3 –(1/2, 3/2)2 0 60 47.842 [3, 5]2 –(1/2, 5/2)3 24 3w 36.998 3 35.551 [2, 6]2 –(1/2, 3/2)1 231 250 48.912 50 46.860 5 44.928 2 36.512 2 35.046 [3, 5]3 –(1/2, 5/2)3 88 50 48.361 30 46.397 2w 36.368 3 34.947
a Calculated transition probabilities in 10
10 (sec
−1 ) for In
23+ .
b Symbols: p, perturbed by close line; u, unresolved shoulder; w, wide.
c Doubly classified.
d Blended with line of Co-like ion.
e Blended with line of Cu-like ion.
f Blended with second-order line of O
7+ .
Table 3
Observed Wavelengths (in Angstroms) for 3p 6 3d 8 –3p 5 3d 9 Transitions in Nd34+ , Sm36+ , Eu37+ , and Gd38+
Transition 3p 6 3d 8 –3p 5 3d 9 Nd34+ Sm36+ Eu37+ Gd38+
gAa Intb λ Int λ Int λ Int λ [4, 4]2 –(3/2, 5/2)2 308 8 42.686 8 40.285 5 39.142 1 38.060 [4, 4]4 –(3/2, 5/2)4 278 5 42.595 6 40.206 5 39.089 1 38.007 [3, 5]2 –(3/2, 3/2)2 356 3 41.941 1w 39.618 3 38.529 [3, 5]4 –(3/2, 3/2)3 387 3 41.627 6 39.298 4 38.208 1 37.147 [3, 5]1 –(3/2, 3/2)1 55 2 39.200 [4, 4]2 –(3/2, 5/2)3 45 2 38.896 [3, 5]3 –(3/2, 3/2)2 356 5 41.028 5 38.754 3 37.672c 2 36.643c [3, 5]2 –(3/2, 3/2)1 224 3 40.964 3 38.720 3 37.672c 2 36.643c [4, 4]4 –(3/2, 5/2)3 757 15 40.336 25 38.058 20w 36.994 15 35.978 [3, 5]3 –(3/2, 3/2)3 182 3 40.071 4 37.858 2 36.826 [4, 4]2 –(3/2, 5/2)1 159 3 40.005 3 37.760 1 36.705 [4, 4]4 –(3/2, 3/2)3 95 1w 35.022 [2, 6]2 –(1/2, 3/2)2 498 3 32.916 4 30.302 5 29.083 [3, 5]1 –(1/2, 5/2)2 306 2 32.500 2 29.941 2 28.738 [3, 5]2 –(1/2, 5/2)2 381 2 32.176 2w 29.651 2 28.469 1 27.352 [3, 5]4 –(1/2, 5/2)3 1446 10 31.946 20 29.467 7 28.304 1 27.197 [3, 5]3 –(1/2, 5/2)2 387 31.633d 29.160d 28.006d [3, 5]2 –(1/2, 5/2)3 97 4u 29.115 [2, 6]2 –(1/2, 3/2)1 564 5 31.030c 8 28.646c 1 27.539c 1 26.461c [3, 5]3 –(1/2, 5/2)3 322 5 31.030c 8 28.646c 1 27.539c 1 26.461c
a Calculated transition probabilities in 10
10 (sec
−1 ) for Nd
34+ .
b Symbol: w, wide.
c Doubly classified.
d Blended with line of Co-like ion.
Table 4
Energy Levels (in 1000 cm−1 ) of the 3p 6 3d 8 and 3p 5 3d 9 Configurations in Ru18+ , Rh19+ , Pd20+ , Ag21+ , and Cd22+
Designation J Ru18+ Rh19+ Pd20+ Ag21+ Cd22+ 3p 6 3d 8 [4, 4] 4 0.00 0.00 0.00 0.00 0.00 [4, 4] 2 31.07 32.83 34.74 36.46 37.89 [4, 4] 0 77.69 82.53 87.66 92.53 97.55 [3, 5] 3 32.03 36.52 41.49 47.03 52.95 [3, 5] 2 60.90 66.67 73.12 80.06 87.45 [3, 5] 1 82.20 88.72 95.93 103.49 111.44 [3, 5] 4 94.47 101.07 107.98 115.75 123.65 [2, 6] 2 94.51 103.99 114.59 126.28 138.75 [2, 6] 0 200.07 212.83 226.56 241.31 256.85 3p 5 3d 9 (3/2, 5/2) 4 1373.07 1428.86 1484.86 1541.67 1598.99 (3/2, 5/2) 2 1394.93 1452.28 1510.16 1568.58 1627.55 (3/2, 5/2) 3 1430.04 1490.20 1551.00 1612.37 1674.36 (3/2, 5/2) 1 1474.03 1535.85 1598.44 1661.76 1725.75 (3/2, 3/2) 2 1464.91 1526.98 1590.07 1654.35 1719.51 (3/2, 3/2) 0 1481.13 1544.32 1608.60 1674.08 1740.44 (3/2, 3/2) 3 1495.79 1559.94 1624.79 1690.89 1758.02 (3/2, 3/2) 1 1516.03 1579.20 1643.00 1707.67 1773.17 (1/2, 5/2) 2 1626.61 1707.62 1791.09 1877.36 1966.78 (1/2, 5/2) 3 1698.67 1779.04 1861.67 1947.46 2035.96 (1/2, 3/2) 2 1604.46 1688.12 1774.82 1864.94 1958.42 (1/2, 3/2) 1 1729.10 1816.08 1906.03 1999.54 2096.56 Uncertainty 0.15 0.15 0.15 0.20 0.20
Table 5
Energy Levels (in 1000 cm−1 ) of the 3p 6 3d 8 and 3p 5 3d 9 configurations in In23+ , Sn24+ , Sb25+ , Xe28+ , and Ba30+
Designation J In23+ Sn24+ Sb25+ Xe28+ Ba30+ 3p 6 3d 8 [4, 4] 4 0.00 0.00 0.00 0.00 0.00 [4, 4] 2 39.59 40.77 42.67 46.62 49.02 + x [4, 4] 0 102.72 107.72 (112.89) (128.31) (138.56) [3, 5] 3 59.62 66.66 74.67 101.72 124.57 [3, 5] 2 95.73 104.16 113.64 145.81 171.67 [3, 5] 1 120.27 129.32 139.37 (173.24) 199.77 + y [3, 5] 4 132.32 141.31 150.93 183.99 210.87 [2, 6] 2 152.70 167.43 183.84 + x 241.33 + x 287.54 + z [2, 6] 0 273.59 291.39 (310.58) (376.52) (428.35) 3p 5 3d 9 (3/2, 5/2) 4 1656.92 1715.48 1774.72 1957.52 2083.77 (3/2, 5/2) 2 1687.33 1747.41 1808.64 1996.51 2125.99 + x (3/2, 5/2) 3 1737.01 1800.31 1864.18 2060.79 2196.69 (3/2, 5/2) 1 1790.63 1855.85 (1922.10) 2124.97 2264.50 + x (3/2, 3/2) 2 1785.94 1853.37 1922.35 2137.34 2290.23 (3/2, 3/2) 0 1808.18 1876.99 (1947.54) (2167.61) (2322.63) (3/2,3/2) 3 1826.28 1895.59 1966.14 2186.37 2342.80 (3/2, 3/2) 1 1839.90 1907.32 1976.57 2191.85 2345.21 (1/2, 5/2) 2 2059.33 2153.90 2253.27 (2574.12) 2809.10 + y (1/2, 5/2) 3 2127.49 2222.07 2320.13 2639.15 2874.27 (1/2, 3/2) 2 2055.65 2156.99 2262.06 + x 2604.84 + x (2860.06) (1/2, 3/2) 1 2197.19 2301.45 2409.62 + x (2765.09) 3026.37 + z Uncertainty 0.25 0.25 0.35 0.50 0.50
Table 6
Energy Levels (in 1000 cm−1 ) of the 3p 6 3d 8 and 3p 5 3d 9 Configurations in La31+ , Nd34+ , Sm36+ , Eu37+ , and Gd38+
Designation J La31+ Nd34+ Sm36+ Eu37+ Gd38+ 3p 6 3d 8 [4, 4] 4 0.00 0.00 0.00 0.00 0.00 [4, 4] 2 50.28 + x 54.05 + x 56.61 57.80 + x (59.03) [4, 4] 0 (143.66) (158.91) (169.01) (174.05) (179.07) [3, 5] 3 136.97 + y 179.98 + y 213.83 232.41 + y (252.19) [3, 5] 2 185.50 + y 233.17 + y 270.01 290.21 + y (311.54) [3, 5] 1 214.32 + y 263.73 + y 301.79 322.63 + y (344.59) [3, 5] 4 224.64 + y 272.96 + y 310.79 330.55 + y (352.11) [2, 6] 2 313.26 + z 401.81 + z 471.23 + x 509.33 + z (549.81) [2, 6] 0 (456.88) (554.05) (629.33) (670.40) (713.88) 3p 5 3d 9 (3/2, 5/2) 4 2147.90 2347.69 2487.18 2558.26 2631.12 (3/2, 5/2) 2 2192.07 + x 2396.74 + x 2538.93 2612.60 + x (2686.45) (3/2, 5/2) 3 2265.57 2479.17 2627.57 2703.14 2779.51 (3/2, 5/2) 1 2335.58 + x 2553.74 + x 2704.92 2782.22 + x (2861.22) (3/2, 3/2) 2 2368.91 + y 2617.40 + y 2794.16 2885.66 + y (2980.73) (3/2, 3/2) 0 (2402.89) (2655.83) (2835.49) (2928.94) (3024.90) (3/2, 3/2) 3 2422.15 + y 2675.40 + y 2855.37 2947.84 + y (3044.12) (3/2, 3/2) 1 2424.09 + y 2674.34 + y 2852.77 2944.70 + y (3040.50) (1/2, 5/2) 2 2935.25 + y 3340.87 + y 3642.23 3802.57 + y (3968.21) (1/2, 5/2) 3 2998.43 + y 3403.19 + y 3704.59 3863.62 + y (4030.29) (1/2, 3/2) 2 (2995.65) 3439.95 + z 3771.34 + x 3947.76 + z (4131.52) (1/2, 3/2) 1 3166.65 + z (3622.73) (3961.52) 4140.76 + z (4331.19) Uncertainty 0.50 0.60 0.75 1.00 1.00
Table 7
Eigenvector Compositions for Ru18+ , Xe28+ , and Gd38+
Level Percentage Composition 3p 6 3d 8 [4, 4]4 90, 95, 98%, [4,4] + 10, 5, 2% [3, 5] [3, 5]4 90, 95, 98%, [3, 5] + 10, 5, 2% [4,4] [3, 5]3 100, 100, 100%, [3, 5] [4, 4]2 77, 97, 99%, [4, 4] + 15, 2, 1% [3, 5] [3, 5]2 53, 90, 97%, [3, 5] + 24, 7, 2% [2, 6] [2,6]2 68, 92, 98%, [2,6] + 32, 7, 2% [3, 5] [3, 5]1 100, 100, 100%, [3, 5] [4, 4]0 71, 89, 96%, [4, 4] + 29,11,4% [2, 6] [2, 6]0 71, 89, 96%, [2, 6] + 29,11, 4% [4, 4] 3p 5 3d 9 (3/2, 5/2)4 100, 100, 100% (3/2, 5/2) (3/2, 5/2)3 30, 68, 89%, (3/2, 5/2) + 63, 31, 11% (3/2, 3/2) (3/2, 3/2)3 17, 61, 87%, (3/2, 3/2) + 64, 31, 11% (3/2, 5/2) (1/2, 5/2)3 74, 91, 97%, (1/2, 5/2) + 21, 8, 3% (3/2, 3/2) (3/2, 5/2)2 78, 91, 97%, (3/2, 5/2) + 21, 8, 3% (3/2, 3/2) (3/2, 3/2)2 76, 91, 97%, (3/2, 3/2) + 21, 8, 3% (3/2,5/2) (1/2, 5/2)2 97, 99,100%, (1/2, 5/2) + 2, 0, 0% (3/2, 3/2) (1/2, 3/2)2 98, 99,100%, (1/2, 3/2) + 2, 0, 0% (3/2, 3/2) (3/2, 5/2)1 36, 74, 95%, (3/2, 5/2) + 65, 25, 5% (3/2, 3/2) (3/2, 3/2)1 35, 75, 95%, (3/2, 3/2) + 59, 24, 5% (3/2, 5/2) (1/2, 3/2)1 93, 98, 99%, (1/2, 3/2) + 6, 1, 0% (3/2, 5/2) (3/2, 3/2)0 100, 100, 100%, (3/2, 3/2)
Table 8
Formulas and Fitted Constants for the Differences Between Observed and Calculated Level Values
Level Formula 3p 6 3d 8 [4, 4]4 ΔE = 0.00 [4, 4]2 ΔE = −1.23 + 16.2(Z − 27.31)−1 [4, 4]0 ΔE = −3.24 + 0.0271Z [3, 5]3 ΔE = 2.62 − 0.1350Z + 0.001849Z 2 [3, 5]2 ΔE = 1.73 − 0.1355Z + 0.001628Z 2 [3, 5]1 ΔE = −2.18 + 0.0013Z [3, 5]4 ΔE = −4.81 + 0.0309Z [2, 6]2 ΔE = −5.06 + 0.1045Z [2,6]0 ΔE = 0.395 + 0.0010Z 3p 5 3d 9 (3/2, 5/2)4 ΔE = −4.98 − 0.0436Z − 198.3(Z − 8.29)−1 (3/2, 5/2)2 ΔE = −28.47 + 0.3712Z − 0.003865Z 2 (3/2, 5/2)3 ΔE = −53.05 + 1539.3(Z + 2.21)−1 (3/2, 5/2)1 ΔE = 26.57 − 0.3070Z − 2736.9(Z + 25.66)−1 (3/2, 3/2)2 ΔE = −23.93 − 0.2348Z + 0.003752Z 2 (3/2, 3/2)0 ΔE = −32.93 + 0.1645Z (3/2, 3/2)3 ΔE = −11.14 − 525.4(Z − 15.00)−1 (3/2, 3/2)1 ΔE = −13.77 − 0.1331Z − 247.2(Z − 20.32)−1 (1/2, 5/2)2 ΔE = −27.36 − 29.5(Z − 32.17)−1 (1/2,5/2)3 ΔE = −6.85 − 1793.3(Z + 12.16)−1 (1/2, 3/2)2 ΔE = −11.19 − 82.2(Z − 29.07)−1 (1/2, 3/2)1 ΔE = −28.25 + 0.0028Z
Table 9
Predicted Energy-Level Values (in 1000 cm−1 ) of the 3p 6 3d 8 and 3p 5 3d 9 Configurations
Designation J Te26+ I27+ Cs29+ Ce32+ Pr33+ pm35+ 3p 6 3d 8 [4, 4] 4 0.00 0.00 0.00 0.00 0.00 0.00 [4, 4] 2 43.76 45.10 47.72 51.53 52.78 55.27 [4, 4] 0 118.03 123.18 133.44 148.76 153 84 163 96 [3, 5] 3 83.05 92.26 112.95 150.32 164.64 196.33 [3, 5] 2 123.73 134.51 158.36 199.43 216.29 251 07 [3, 5] 1 149.90 161.19 186.09 229.81 246.27 282.24 [3, 5] 4 161.54 172.62 197.00 239.79 272.96 291.08 [2, 6] 2 201.52 220.67 263.60 340.82 369.31 435.42 [2, 6] 0 331.10 353.05 401.59 487.30 519.65 590.57 3p 5 3d 9 (3/2, 5/2) 4 1834.88 1895.74 2020.01 2213.56 2280.17 2416.85 (3/2, 5/2) 2 1870.36 1932.92 2060.60 2259.17 2327.42 2467.32 (3/2, 5/2) 3 1929.21 1994.79 2128.45 2335.78 2406.89 2552.43 (3/2, 5/2) 1 1989.03 2056.71 2194.39 2407.25 2480.10 2628.98 (3/2, 3/2) 2 1992.73 2064.60 2213.21 2449.69 2532.49 2704.65 (3/2, 3/2) 0 2019.35 2092.67 2244.22 2485.12 2569.41 2744 49 (3/2, 3/2) 3 2038.38 2111.97 2263.93 2505.27 2588.56 2761.89 (3/2, 3/2) 1 2046.92 2118.86 2267.78 2505.16 2589.50 2764 60 (1/2, 5/2) 2 2355.67 2463.03 2689.54 3064.55 3200.00 3488.21 (1/2, 5/2) 3 2422.96 2529.15 2754.39 3128.05 3263 16 3550 85 (1/2, 3/2) 2 2372.77 2486.60 2730.18 3137.28 3285 24 3601 44 (1/2, 3/2) 1 2524.06 2642.09 2893.30 3312.09 3464.06 3788.43
Table 10
Predicted Energy-Level Values (in 1000 cm−1 ) of the 3p 6 3d 8 and 3p 5 3d 9 Configurations
Designation J Tb39+ Dy40+ Ho41+ Er42+ Tm43+ Yb44+ 3p 6 3d 8 [4, 4] 4 0.00 0.00 0.00 0.00 0.00 0.00 [4, 4] 2 60.27 61.54 62.80 64.08 65.37 66.66 [4, 4] 0 184.10 189.12 194.13 199.16 204 28 209 21 [3, 5] 3 273.22 295.54 319.21 344.26 370.77 398.77 [3, 5] 2 334.09 357.94 383.12 409.70 437 72 467 34 [3, 5] 1 367.81 392.33 418.21 445.48 474.22 504 47 [3, 5] 4 374.85 398.86 424.20 450.93 479 10 508 77 [2, 6] 2 592.77 638.32 686.54 737 57 791 48 848 39 [2, 6] 0 759.88 808.49 859.82 913.98 971.06 1031.17 3p 5 3d 9 (3/2, 5/2) 4 2705.42 2781.05 2858.20 2936.90 3017.24 3099.26 (3/2, 5/2) 2 2762.20 2839.37 2918.04 2998.27 3080.10 3163.61 (3/2, 5/2) 3 2858.24 2938.08 3019.39 3102.25 3186.70 3272 81 (3/2, 5/2) 1 2941.17 3022.60 3105.51 3189.94 3275 99 3363 71 (3/2, 3/2) 2 3077.92 3177.85 3280.67 3386.45 3495.32 3607 40 (3/2, 3/2) 0 3123.54 3224.91 3329.15 3436.34 3546.63 3660 12 (3/2, 3/2) 3 3138.05 3238.80 3342.43 3449.06 3558.79 3671.73 (3/2, 3/2) 1 3143.42 3244.69 3348.80 3455.86 3565.99 3679.29 (1/2, 5/2) 2 4142.19 4323.72 4513.14 4710.85 4917.20 5132.60 (1/2, 5/2) 3 4204.38 4385.89 4575.35 4773.10 4979.55 5195.08 (1/2, 3/2) 2 4324.52 4526.33 4737.34 4957.97 5188 66 5429 87 (1/2, 3/2) 1 4528.55 4734.78 4950.25 5175.42 5410.71 5656.57
Table 11
Wavelengths and Transition Probabilities for the Strongest Magnetic Dipole Transitions in the 3p 6 3d 8 Configurations of Ru18+ . Xe28+ . and Gd38+
Transition Ru18+ Xe28+ Gd38+
λ (Å)gA (103 sec−1 ) λ (Å)gA (104 sec−1 ) λ (Å)gA (105 sec−1 ) [4, 4]2 –[3, 5]2 3351.3 1.9 1008.2 7.6 396.0 12.0 [4, 4]4 –[3, 5]3 3121.1 5.8 983.1 18.6 396.5 27.5 [3, 5]2 –[2, 6]2 2974.4 2.7 1046.9 5.6 419.7 7.5 [4, 4]2 –[3, 5]1 1955.8 1.4 789.8 4.7 350.2 6.5 [3, 5]3 –[2, 6]2 1600.5 7.3 716.3 21.1 336.0 27 5 [4, 4]4 –[3, 5]4 1058.5 6.6 543.5 12.1 284.0 13.3 [3, 5]1 –[2, 6]0 848.4 8.6 491.9 12.7 270.8 11.7