Abstract

We have applied cavity ring-down spectroscopy (CRDS) to the study of the ¹⁶⁶Er isotope in an atomic beam. These measurements were realized with an external cavity diode laser tuned to the 400.9 nm atomic transition of erbium and a customized high-finesse ring-down optical cavity under vacuum. Erbium atomic beams of different number densities were generated in a tantalum foil micro-crucible within the cavity. Absorbance values of the ¹⁶⁶Er isotope between 3 × 10⁻⁶ and 7 × 10⁻⁵ were measured with a best-case precision on the order of 10⁻⁶, which is remarkable when considering the extreme temperatures at which the measurements were conducted, and the short detection path which is characteristic of collimated atomic beams. Number densities of erbium atoms were inferred to be between 2 × 10⁶ and 6 × 10⁷ cm⁻³. This work demonstrates for the first time the ability of studying dilute atomic beams of refractory materials with high accuracy utilizing CRDS. In these initial studies, we used erbium as a model system, but we expect to extend the proposed approach to the measurement of isotopes of uranium and plutonium for nuclear non-proliferation applications.

© 2023 The Author(s)