Abstract
We have used a time-resolved double-resonance (pump-probe) method to assign the CHD<sub>3</sub> spectra taken by an FT-IR spectrometer at high resolution. The spectra of 2<i>v</i><sub>3</sub>, <i>v</i><sub>3</sub> + <i>v</i><sub>6</sub>, and 2<i>v</i><sub>6</sub> around 2000 cm<sup>−1</sup> were investigated. Collisional processes in the molecule were investigated by the time evolution of the signal and double-resonance spectra.
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