Table I
Range in J and Number of Lines Measured in This Study
Vibrational transition Moleculea Band centerb (cm−1 ) Range in J Number of lines measured 20011 ← 20002 626 2428.52 P (18)–R (22)10 10011 ← 10002 626 2429.37 P (36)–R (64)48 20012 ← 20003 626 2429.46 P (26)–R (30)13 11111 ← 11102c 626 2458.16 P (48)–R (43)73 20003 ← 00001 628 2500.76 P (60)–R (62)109 20002 ← 00001 628 2614.25 P (64)–R (63)109 21102 ← 01101c 628 2618.64 P (47)–R (45)128 10011 ← 10002 628 2415.71 P (22)–R (36)38 21103 ← 01101c 628 2464.98 P (44)–R (44)112 20002 ← 00001 627 2641.24 P (42)–R (44)69 20003 ← 00001 627 2524.25 P (40)–R (38)67 20002 ← 00001 638 2588.18 P (27)–R (36)27
a Molecule codes: 626 =
12 C
16 O
2 , 628 =
16 O
12 C
18 O, 627 =
16 O
12 C
17 O, 638 =
16 O
13 C
18 O.
b Values from Rinsland
et al .
1
c Both
e ′ ←
e ″ and
f ′ ←
f ″ transitions included.
Table II
Line Positions and Observed and Calculated Line Intensities (cm−1 /molecule cm−2 at 296 K) of Carbon Dioxide Bands in the 2395–2680-cm−1 Region
(20002-00001) 627
OBSERVED POSITION LINE INTENSITY LINE OBS. CAL. β (%)W N 2608.51548 P42 .1781E-26 .3156E-26 −43.6 .0040 1 2610.11182 P40 .4184E-26 .4080E-26 2.5 .0067 1 2610.91156 P39 .6195E-26 .4610E-26 34.4 .0085 1 2611.71017 P38 .5056E-26 .5186E-26 −2.5 .0108 1 2612.50025 P37 .4997E-26 .5808E-26 −14.0 .0135 1 2613.29711 P36 .6575E-26 .6477E-26 1.5 .0168 1 2614.09342 P35 .6541E-26 .7191E-26 −9.0 .0207 1 2614.88408 P34 .7699E-26 .7947E-26 −3.1 .0253 1 2617.25928 P31 .9416E-26 .1044E-25 −9.8 .0436 1 2618.04855 P30 .1117E-25 .1132E-25 −1.3 .0513 1 2618.83674 P29 .1293E-25 .1223E-25 5.7 .0598 1 2619.62371 P28 .1524E-25 .1314E-25 16.0 .0691 1 2620.40946 P27 .1467E-25 .1405E-25 4.4 .0790 1 2621.19384 P26 .1536E-25 .1495E-25 2.7 .0976 2 2621.98057 P25 .1623E-25 .1582E-25 2.6 .1001 1 2622.76191 P24 .1736E-25 .1665E-25 4.3 .1110 1 2623.54476 P23 .1734E-25 .1744E-25 −.6 .1217 1 2624.32603 P22 .1918E-25 .1816E-25 5.6 .1319 1 2625.10593 P21 .1942E-25 .1880E-25 3.3 .1545 2 2626.66332 P19 .1970E-25 .1979E-25 −.5 .1712 2 2628.21574 P17 .1854E-25 .2030E-25 −8.7 .1649 1 2629.76519 P15 .2041E-25 .2024E-25 .8 .1791 2 2630.53715 P14 .1992E-25 .1997E-26 −.3 .1743 2 2631.30928 P13 .1977E-25 .1953E-25 1.2 .1667 2 2632.07937 P12 .2082E-25 .1892E-25 10.0 .1564 2 2632.84906 P11 .1840E-25 .1813E-25 1.5 .1314 1 2633.61749 P10 .1833E-25 .1717E-25 6.8 .0179 1 2634.38418 P 9 .1585E-25 .1603E-25 −1.1 .1028 1 2635.15146 P 8 .1443E-25 .1474E-25 −2.1 .0869 1 2636.68042 P 6 .1386E-25 .1169E-25 18.6 .0546 1 2637.44284 P 5 .9449E-26 .9959E-26 −5.1 .0397 1 2638.96296 P 3 .6727E-26 .6180E-26 8.9 .0153 1 2639.72346 P 2 .6456E-26 .4167E-26 54.9 .0069 1 2642.75562 R 1 .6097E-26 .4203E-26 45.1 .0071 1 2643.50260 R 2 .6351E-26 .6259E-26 1.5 .0157 1 2644.25745 R 3 .8713E-26 .8256E-26 5.5 .0273 1 2645.00904 R 4 .1017E-25 .1017E-25 0.0 .0414 1 2646.50949 R 6 .1376E-25 .1368E-25 .6 .0749 1 2647.25687 R 7 .1674E-25 .1525E-25 9.8 .0930 1 2648.00406 R 8 .1587E-25 .1666E-25 −4.7 .1110 1 2649.49524 R10 .1859E-25 .1900E-25 −2.2 .1443 1 2650.23731 R11 .1825E-25 .1991E-25 −8.3 .1585 1 2650.97990 R12 .1838E-25 .2064E-25 −10.9 .1704 1 2651.72159 R13 .2036E-25 .2120E-25 −4.0 .1963 2 2652.46169 R14 .2013E-25 .2157E-25 −6.7 .2034 2 2653.20042 R15 .2294E-25 .2178E-25 5.3 .2074 2 2653.93777 R16 .2301E-25 .2183E-25 5.4 .2082 2 2654.67431 R17 .2221E-25 .2171E-25 2.3 .2061 2 2656.14409 R19 .2199E-25 .2107E-25 4.4 .1775 1 2656.87741 R20 .2200E-25 .2056E-25 7.0 .1690 1 2657.60949 R21 .1760E-25 .1994E-25 −11.7 .1591 1 2658.33876 R22 .1902E-25 .1923E-25 −1.1 .1616 2 2659.06915 R23 .1709E-25 .1844E-25 −7.3 .1361 1 2659.79630 R24 .1622E-26 .1759E-25 −7.8 .1238 1 2661.24895 R26 .1495E-25 .1576E-25 −5.1 .0993 1 2661.97530 R27 .1601E-25 .1480E-25 8.2 .0876 1 2662.69784 R28 .1273E-25 .1383E-25 −8.0 .0765 1 2664.14215 R30 .1057E-25 .1191E-25 −11.3 .0567 1 2664.86249 R31 .8823E-26 .1097E-25 −19.6 .0481 1 2665.58236 R32 .1029E-25 .1006E-25 2.3 .0405 1 2667.01608 R34 .7971E-26 .8344E-26 −4.5 .0278 1 2667.73267 R35 .7362E-26 .7548E-26 −2.5 .0228 1 2668.44837 R36 .7502E-26 .6798E-26 10.4 .0185 1 2669.16145 R37 .5148E-26 .6095E-26 −15.5 .0149 1 2669.87076 R38 .4419E-26 .5441E-26 −18.8 .0118 1 2670.58536 R39 .5666E-26 .4836E-26 17.2 .0094 1 2671.29098 R40 .5337E-26 .4280E-26 24.7 .0073 1 2672.00145 R41 .4743E-26 .3772E-26 25.7 .0057 1 2674.12298 R44 .5941E-26 .2517E-26 136.0 .0025 1
(20011-20002) 626
OBSERVED POSITION LINE INTENSITY LINE OBS. CAL. β (%)W N 2413.86452 P18 .2238E-26 .3024E-26 −26.0 .0037 1 2415.55815 P16 .4383E-26 .3071E-26 42.7 .0038 1 2418.89672 P12 .3739E-26 .2873E-26 30.1 .0033 1 2420.54479 P10 .2489E-26 .2614E-26 −4.8 .0027 1 2435.33848 R 8 .2012E-26 .2543E-26 −20.9 .0026 1 2436.81254 R10 .2226E-26 .2894E-26 −23.1 .0034 1 2439.70358 R14 .2959E-26 .3270E-26 −9.5 .0043 1 2441.13050 R16 .3499E-26 .3297E-26 6.1 .0043 1 2442.53782 R18 .2067E-26 .3230E-26 −36.0 .0042 1 2445.31151 R22 .4118E-26 .2870E-26 43.5 .0033 1
(20003-00001) 627
OBSERVED POSITION LINE INTENSITY LINE OBS. CAL. β (%)W N 2494.81224 P40 .2703E-26 .1809E-26 49.4 .0013 1 2496.96196 P37 .3445E-26 .2576E-26 33.7 .0027 1 2497.68865 P36 .5065E-26 .2872E-26 76.4 .0033 1 2498.41343 P35 .5358E-26 .3189E-26 68.0 .0041 1 2499.13609 P34 .4405E-26 .3524E-26 25.0 .0050 1 2499.85570 P33 .2625E-26 .3877E-26 −32.3 .0060 1 2500.57839 P32 .4093E-26 .4246E-26 −3.6 .0072 1 2501.30370 P31 .4591E-26 .4629E-26 −.8 .0086 1 2502.02902 P30 .5665E-26 .5022E-26 12.8 .0101 1 2503.47758 P28 .5224E-26 .5826E-26 −10.3 .0136 1 2504.20723 P27 .6241E-26 .6230E-26 .2 .0155 1 2504.93496 P26 .6106E-26 .6627E-26 −7.9 .0176 1 2505.66601 P25 .6720E-26 .7014E-26 −4.2 .0197 1 2506.39532 P24 .7067E-26 .7385E-26 −4.3 .0218 1 2507.12724 P23 .7328E-26 .7732E-26 −5.2 .0239 1 2507.85751 P22 .6015E-26 .8052E-26 −25.3 .0259 1 2508.59211 P21 .8416E-26 .8336E-26 1.0 .0278 1 2509.32673 P20 .7764E-26 .8580E-26 −9.5 .0294 1 2510.06090 P19 .7305E-26 .8776E-26 −16.8 .0308 1 2510.79727 P18 .9101E-26 .8918E-26 2.1 .0318 1 2511.53380 P17 .7420E-26 .9003E-26 −17.6 .0324 1 2512.27428 P16 .9888E-26 .9023E-26 9.6 .0326 1 2513.01286 P15 .8341E-26 .8974E-26 −7.1 .0322 1 2513.75623 P14 .8977E-26 .8854E-26 1.4 .0314 1 2514.49492 P13 .8844E-26 .8659E-26 2.1 .0300 1 2515.24104 P12 .8682E-26 .8387E-26 3.5 .0281 1 2515.98393 P11 .6477E-26 .8038E-26 −19.4 .0258 1 2516.72938 P10 .9062E-26 .7611E-26 19.1 .0232 1 2517.47632 P 9 .6618E-26 .7109E-26 −6.9 .0202 1 2518.22402 P 8 .5270E-26 .6534E-26 −19.3 .0171 1 2518.97451 P 7 .5991E-26 .5890E-26 1.7 .0139 1 2519.72248 P 6 .6033E-26 .5182E-26 16.4 .0107 1 2520.47429 P 5 .4170E-26 .4416E-26 −5.6 .0078 1 2521.22640 P 4 .2784E-26 .3599E-26 −22.6 .0052 1 2521.98331 P 3 .3548E-26 .2740E-26 29.5 .0030 1 2526.52943 R 2 .3738E-26 .2776E-26 34.7 .0031 1 2527.28639 R 3 .3800E-26 .3661E-26 3.8 .0054 1 2528.05437 R 4 .3688E-26 .4511E-26 −18.2 .0081 1 2528.81741 R 5 .4858E-26 .5316E-26 −8.6 .0113 1 2529.57933 R 6 .7678E-26 .6069E-26 26.5 .0147 1 2530.34621 R 7 .4977E-26 .6761E-26 −26.4 .0183 1 2531.11559 R 8 .5938E-26 .7388E-26 −19.6 .0218 1 2531.88283 R 9 .7575E-26 .7944E-26 −4.6 .0252 1 2532.65328 R10 .9477E-26 .8425E-26 12.5 .0284 1 2533.42405 R11 .1083E-25 .8829E-26 22.7 .0312 1 2534.19881 R12 .8551E-26 .9154E-26 −6.6 .0335 1 2534.97061 R13 .5057E-26 .9401E-26 −14.3 .0354 1 2535.74334 R14 .9193E-26 .9569E-26 −3.9 .0366 1 2538.84932 R18 .1156E-25 .9519E-26 21.4 .0362 1 2539.63124 R19 .1155E-25 .9346E-26 23.6 .0349 1 2540.41022 R20 .1059E-25 .9120E-26 16.1 .0333 1 2541.18914 R21 .7598E-26 .8847E-26 −14.1 .0313 1 2541.97164 R22 .7743E-26 .8532E-26 −9.2 .0291 1 2542.75394 R23 .1011E-25 .8183E-26 23.5 .0268 1 2543.53775 R24 .8714E-26 .7806E-26 11.6 .0244 1 2544.32136 R26 .8643E-26 .7407E-26 16.7 .0219 1 2545.10495 R26 .5868E-26 .6993E-26 −16.1 .0196 1 2545.89130 R27 .4503E-26 .6568E-26 −31.4 .0173 1 2546.67621 R28 .4188E-26 .6139E-26 −31.8 .0151 1 2547.46339 R29 .5860E-26 .5709E-26 2.6 .0130 1 2548.25216 R30 .7598E-26 .5285E-26 43.8 .0112 1 2549.04177 R31 .4168E-26 .4869E-26 −14.4 .0095 1 2549.82751 R32 .6182E-26 .4465E-26 38.5 .0080 1 2551.40808 R34 .8049E-26 .3704E-26 117.3 .0055 1 2552.19512 R35 .2774E-26 .3350E-26 −17.2 .0045 1 2553.77996 R37 .1216E-26 .2706E-26 −55.1 .0029 1 2554.57013 R38 .2461E-26 .2415E-26 1.9 .0023 1
(20012-20003) 626
OBSERVED POSITION LINE INTENSITY LINE OBS. CAL. β (%)W N 2406.18870 P26 .2097E-26 .3539E-26 −40.7 .0050 1 2408.19385 P24 .3472E-26 .3969E-26 −12.5 .0063 1 2410.16165 P22 .5000E-26 .4353E-26 14.9 .0076 1 2412.09630 P20 .4682E-26 .4664E-26 .4 .0087 1 2413.99750 P18 .4662E-26 .4872E-26 −4.3 .0095 1 2415.86095 P16 .4873E-26 .4951E-26 −1.6 .0098 1 2417.68909 P14 .7424E-26 .4877E-26 52.2 .0095 1 2440.10299 R14 .4665E-26 .5274E-26 −11.5 .0111 1 2441.36577 R16 .5396E-26 .5316E-26 1.5 .0113 1 2444.93747 R22 .3546E-26 .4617E-26 −23.2 .0085 1 2446.05829 R24 .4262E-26 .4199E-26 1.5 .0071 1 2447.13979 R26 .3710E-26 .3738E-26 −.7 .0056 1 2449.22447 R30 .3048E-26 .2785E-26 −.7 .0031 1
(11111-11102) 626
OBSERVED POSITION LINE INTENSITY LINE OBS. CAL. β (%)W N 2413.01631 P48 .2081E-26 .2034E-26 2.3 .0017 1 2416.44587 P45 .2845E-26 .3251E-26 −12.5 .0042 1 2417.33527 P44 .3944E-26 .3722E-26 6.0 .0055 1 2418.58066 P43 .4293E-26 .4319E-26 −..6 .0075 1 2419.46228 P42 .5636E-26 .4906E-26 14.9 .0096 1 2420.68387 P41 .5703E-26 .5639E-26 1.1 .0127 1 2421.55905 P40 .4087E-26 .6354E-26 −35.7 .0161 1 2422.76075 P39 .6664E-26 .7235E-26 −7.9 .0209 1 2423.63751 P38 .5268E-26 .8085E-26 −34.8 .0261 1 2425.68903 P36 .9119E-26 .1010E-25 −9.7 .0408 1 2426.84506 P35 .9930E-26 .1128E-25 −12.0 .0509 1 2427.71592 P34 .9903E-26 .1240E-25 −20.1 .0615 1 2428.85156 P33 .1413E-25 .1371E-25 3.1 .0752 1 2429.71819 P32 .1446E-25 .1493E-25 −3.1 .0892 1 2430.82822 P31 .1768E-25 .1634E-25 8.2 .1167 2 2432.78204 P29 .1975E-25 .1911E-25 3.3 .1460 1 2433.64615 P28 .2065E-25 .2043E-25 1.1 .1824 2 2434.70960 P27 .2104E-25 .2190E-2S −3.9 .1918 1 2435.57165 P26 .2267E-25 .2319E-25 −2.2 .2350 2 2436.61070 P25 .2502E-25 .2458E-25 1.8 .2641 2 2438.48742 P23 .2697E-25 .2700E-25 −.1 .3186 2 2439.34217 P22 .2639E-25 .2799E-25 −5.7 .3424 2 2440.33774 P21 .2812E-25 .2898E-25 −3.0 .3671 2 2443.00762 P18 .3084E-25 .3072E-25 .4 .4125 2 2443.95853 P17 .3219E-25 .3097E-25 3.9 .4192 2 2444.79962 P16 .3054E-25 .3090E-25 −1.2 .4174 2 2445.72903 P15 .3112E-25 .3067E-25 1.5 .4112 2 2447.47338 P13 .2972E-25 .2938E-25 1.2 .3772 2 2448.30246 P12 .3088E-25 .2831E-25 9.1 .3503 2 2449.19187 P11 .2822E-25 .2703E-25 4.4 .3192 2 2450.01432 P10 .2564E-25 .2545E-25 .7 .2830 2 2450.88143 P 9 .2437E-25 .2364E-25 3.1 .2442 2 2451.69812 P 8 .2114E-25 .2157E-25 −2.0 .2033 2 2452.54610 P 7 .1882E-25 .1928E-25 −2.4 .1486 1 2453.35400 P 6 .1526E-25 .1676E-25 −8.9 .1124 1 2454.18322 P 5 .1519E-25 .1405E-25 8.1 .0790 1 2454.98317 P 4 .1077E-25 .1113E-25 −3.2 .0496 1 2455.79311 P 3 .7796E-26 .8003E-26 −2.6 .0256 1 2459.70171 R 1 .4989E-26 .4484E-26 11.3 .0080 1 2460.46586 R 2 .7609E-26 .7874E-26 −3.4 .0248 1 2461.21679 R 3 .1146E-25 .1090E-25 5.1 .0475 1 2461.97190 R 4 .1453E-25 .1367E-25 6.3 .0748 1 2462.70553 R 5 .1714E-25 .1623E-25 5.6 .1053 1 2463.44809 R 6 .2045E-25 .1855E-25 10.2 .1377 1 2464.16654 R 7 .2315E-25 .2065E-25 12.1 .1865 2 2464.89786 R 8 .2392E-25 .2250E-25 6.3 .2025 1 2465.60049 R 9 .2550E-25 .2411E-25 5.8 .2541 2 2466.31947 R10 .2312E-25 .2545E-25 −9.2 .2830 2 2467.00797 R11 .2484E-25 .2654E-25 −6.4 .3080 2 2467.71410 R12 .2629E-25 .2735E-25 −3.9 .3270 2 2468.38860 R13 .2776E-25 .2795E-25 −.7 .3413 2 2469.08014 R14 .2835E-25 .2824E-25 .4 .3487 2 2469.74226 R15 .2866E-25 .2836E-25 1.1 .3516 2 2470.41892 R16 .2764E-25 .2820E-25 −2.0 .3476 2 2471.06813 R17 .2716E-25 .2790E-25 −2.7 .3402 2 2473.01485 R20 .2602E-25 .2580E-25 .9 .2910 2 2473.64015 R21 .2470E-25 .2489E-25 −.8 .2707 2 2474.27199 R22 .2009E-25 .2376E-25 −15.4 .0209 1 2474.88702 R23 .2256E-25 .2267E-25 −.5 .2246 2 2475.50177 R24 .2289E-25 .2139E-25 7.0 .2000 2 2476.10636 R2S .2014E-25 .2019E-25 −.2 .1630 1 2476.70660 R26 .1828E-25 .1884E-25 −3.0 .1420 1 2477.29896 R27 .1748E-25 .1760E-25 −.7 .1240 1 2477.88182 R28 .1536E-25 .1625E-25 −5.5 .1057 1 2479.03216 R30 .1245E-25 .1374E-25 −9.4 .0755 1 2479.60620 R31 .1299E-25 .1260E-25 2.5 .0635 1 2480.15678 R32 .1210E-25 .1139E-25 6.2 .0519 1 2481.25349 R34 .8076E-26 .9271E-26 −12.9 .0344 1 2482.32704 R36 .7201E-26 .7404E-26 −2.7 .0219 1 2482.86858 R37 .6162E-26 .6614E-26 −6.8 .0175 1 2483.90472 R39 .4850E-26 .5144E-26 −5.7 .0106 1 2484.91460 R41 .2800E-26 .3931E-26 −28.8 .0062 1 2485.90436 R43 .3993E-26 .2952E-26 35.3 .0035 1
(20002-00001) 627
OBSERVED POSITION LINE INTENSITY LINE OBS. CAL. β (%)W N 2567.87590 P27 .2922E-26 .3003E-26 −2.7 .0036 1 2570.17828 P24 .3460E-26 .3532E-26 −2.0 .0050 1 2571.70472 P22 .5851E-26 .3832E-26 52.7 .0059 1 2572.46304 P21 .4234E-26 .3959E-26 6.9 .0063 1 2574.74386 P18 .2678E-26 .4210E-26 −36.4 .0071 1 2576.25867 P16 .3021E-26 .4244E-26 −28.8 .0072 1 2577.76357 P14 .4687E-26 .4152E-26 12.9 .0069 1 2578.51325 P13 .5020E-26 .4054E-26 23.8 .0066 1 2579.26385 P12 .4246E-26 .3922E-26 8.3 .0062 1 2580.76697 P10 .6730E-26 .3551E-26 89.5 .0050 1 2581.51075 P 9 .3461E-26 .3313E-26 4.5 .0044 1 2583.00454 P 7 .2336E-26 .2740E-26 −14.7 .0030 1 2596.20397 R10 .3294E-26 .3929E-26 −16.2 .0062 1 2598.36485 R13 .3503E-26 .4400E-26 −20.4 .0077 1 2599.08086 R14 .2933E-26 .4485E-26 −34.6 .0080 1 2599.79617 R15 .4179E-26 .4535E-26 −7.9 .0082 1 2600.51075 R16 .4658E-26 .4552E-26 2.3 .0083 1 2601.22567 R17 .4217E-26 .4536E-26 −7.0 .0082 1 2601.94003 R18 .4808E-26 .4491E-26 7.1 .0081 1 2602.64998 R19 .3995E-26 .4418E-26 −9.6 .0078 1 2603.35751 R20 .4210E-26 .4319E-26 −2.6 .0075 1 2605.47946 R23 .3451E-26 .3901E-26 −11.5 .0061 1 2606.18884 R24 .4241E-26 .3730E-26 13.7 .0056 1 2610.38959 R30 .2276E-26 .2567E-26 −11.3 .0026 1 2611.08194 R31 .1629E-26 .2373E-26 −31.4 .0023 1 2611.77483 R32 .2312E-26 .2183E-26 5.9 .0019 1 2614.51114 R36 .4309E-26 .1496E-26 188.0 .0009 1
(10011–10002) 626
OBSERVED POSITION LINE INTUNSITY LINE OBS. CAL. β (%)W N 2397.04790 P36 .7792E-24 .7727E-24 .8 2.0000 2 2399.06300 P34 .9550E-24 .9543E-24 .1 2.0000 2 2401.05353 P32 .1153E-23 .1156E-23 −.3 2.0000 2 2403.01926 P30 .1385E-23 .1375E-23 .7 2.0000 2 2406.87509 P26 .1822E-23 .1828E-23 −.3 2.0000 2 2408.76469 P24 .2046E-23 .2043E-23 .1 2.0000 2 2410.62845 P22 .2150E-23 .2233E-23 −3.7 2.0000 2 2412.46613 P20 .2391E-23 .2382E-23 .4 2.0000 2 2414.27754 P18 .2490E-23 .2478E-23 .5 2.0000 2 2416.06249 P16 .2496E-23 .2507E-23 −.4 2.0000 2 2417.82085 PI 4 .2471E-23 .2458E-23 .5 2.0000 2 2419.55239 P12 .2303E-23 .2324E-23 −.9 2.0000 2 2421.25708 P10 .2116E-23 .2104E-23 .6 2.0000 2 2424.58528 P 6 .1436E-23 .1423E-23 .9 2.0000 2 2426.20864 P 4 .9885E-24 .9838E-24 .5 2.0000 2 2427.80470 P 2 .5026E-24 .5023E-24 .1 2.0000 2 2430.14768 R 0 .2538E-24 .2518E-24 .8 2.0000 2 2431.67533 R 2 .7490E-24 .7421E-24 .9 2.0000 2 2433.17569 R 4 .1212E-23 .1197E-23 1.3 2.0000 2 2434.64868 R 6 .1606E-23 .1595E-23 .7 2.0000 2 2436.09433 R 8 .1933E-23 .1924E-23 .5 2.0000 2 2437.51268 R10 .2168E-23 .2171E-23 −.1 2.0000 2 2438.90378 R12 .2324E-23 .2333E-23 −.4 2.0000 2 2440.26771 R14 .2389E-23 .2410E-23 −.9 2.0000 2 2441.60455 R16 .2392E-23 .2407E-23 −.6 2.0000 2 2442.91443 R18 .2318E-23 .2335E-23 −.7 2.0000 2 2444.19744 R20 .2210E-23 .2206E-23 .2 2.0000 2 2445.45379 R22 .2025E-23 .2033E-23 −.4 2.0000 2 2446.68348 R24 .1830E-23 .1830E-23 0.0 2.0000 2 2447.88679 R26 .1589E-23 .1612E-23 −1.4 2.0000 2 2449.06395 R28 .1377E-23 .1391E-23 −1.0 2.0000 2 2450.21509 R30 .1164E-23 .1176E-23 −1.0 2.0000 2 2451.34048 R32 .9770E-24 .9745E-24 .3 2.0000 2 2452.44025 R34 .7930E-24 .7923E-24 .1 2.0000 2 2463.51482 R36 .6309E-24 .6322E-24 −.2 2.0000 2 2454.56429 R38 .4959E-24 .4953E-24 .1 2.0000 2 2455.58902 R40 .3794E-24 .3810E-24 −.4 2.0000 2 2457.56558 R44 .2155E-24 .2137E-24 .8 2.0000 2 2458.51842 R46 .1586E-24 .1559E-24 1.7 1.9008 2 2459.44723 R48 .1147E-24 .1118E-24 2.6 1.4631 2 2460.35337 R50 .8127E-25 .7877E-25 3.2 1.2300 2 2461.23680 R52 .5343E-25 .5457E-25 −2.1 1.1104 2 2462.09733 R54 .3650E-25 .3717E-25 −1.8 .6039 2 2462.93704 R56 .2218E-25 .2490E-25 −10.9 .2480 1 2463.75410 R58 .1564E-25 .1640E-25 −4.6 .1076 1 2464.55214 R60 .1005E-25 .1062E-25 −5.4 .0451 1 2465.32885 R62 .5727E-26 .6767E-26 −15.4 .0183 1 2466.08252 R64 .5101E-26 .4240E-26 20.3 .0072 1
(10011-10002) 628
OBSERVED POSITION LINE INTENSITY LINE OBS. CAL. β (%)W N 2398.34498 P22 .4567E-26 .5140E-26 −11.1 .0106 I 2399.18831 P21 .6463E-26 .5310E-26 21.7 .0113 1 2400.02553 P20 .4166E-26 .5454E-26 −23.6 .0119 1 2400.85607 P19 .4396E-26 .5567E-26 −21.0 .0124 1 2401.68067 P18 .4160E-26 .5647E-26 −26.3 .0128 1 2402.50395 P17 .6292E-26 .5690E-26 10.6 .0130 1 2403.32273 P16 .6966E-26 .5694E-26 22.3 .0130 1 2405.74357 P13 .6907E-26 .5440E-26 27.0 .0118 1 2406.53995 P12 .5279E-26 .5262E-26 .3 .01)1 1 2407.33076 P11 .6925E-26 .5037E-26 37.5 .0101 1 2408.11784 P10 .5123E-26 .4764E-26 7S .0091 1 2408.89931 P 9 .6149E-26 .4445E-26 38.3 .0079 1 2409.66814 P 8 .4237E-26 .4082E-26 3.8 .0067 1 2410.44516 P 7 .3894E-26 .3677E-26 5.9 .0054 1 2411.21410 P 6 .5482E-26 .3233E-26 69.6 .0042 1 2412.73480 P 4 .1408E-26 .2243E-26 −37.2 .0020 1 2419.31496 R 4 .3878E-26 .2811E-26 38.0 .0032 1 2420.71783 R 6 .4000E-26 .3786E-26 5.7 .0057 1 2421.41227 R 7 .4009E-26 .4221E-26 −5.0 .0071 1 2422.78802 R 9 .4553E-26 .4968E-26 −8.4 .0099 1 2423.46860 R10 .5933E-26 .5274E-26 12.5 .0111 1 2424.14116 R11 .4472E-26 .5533E-26 −19.2 .0122 1 2425.48414 R13 .5669E-26 .5906E-26 −4.0 .0140 1 2426.13737 R14 .4974E-26 .6020E-26 −17.4 .0145 1 2426.79192 R15 .7098E-26 .6088E-26 16.6 .0148 1 2427.44259 R16 .5551E-26 .6110E-26 −9.1 .0149 1 2428.08657 R17 .4673E-26 .6089E-26 −23.3 .0148 1 2428.72902 R18 .6257E-26 .6028E-26 3.8 .0145 1 2429.36190 R19 .4617E-26 .5930E-26 −22.1 .0141 1 2429.99730 R20 .6153E-26 .5798E-26 6.1 .0134 1 2431.23683 R22 .6373E-26 .5448E-26 17.0 .0119 1 2431.85192 R23 .4077E-26 .5237E-26 −22.2 .0110 1 2432.46246 R24 .6878E-26 .5008E-26 37.3 .0100 1 2433.06729 R25 .2931E-26 .4764E-26 −38.5 .0091 1 2434.26021 R27 .3775E-26 .4246E-26 −11.1 .0072 1 2434.85390 R28 .3528E-26 .3980E-26 −11.4 .0063 1 2437.16942 R32 .2404E-26 .2930E-26 −18.0 .0034 1 2439.41001 R36 .1828E-26 .2008E-26 −9.0 .0016 1
(20003-00001) 628
OBSERVED POSITION LINE INTENSITY LINE OBS. CAL. β (%)W N 2457.29440 P60 .3596E-26 .2222E-26 61.8 .0020 1 2468.73308 P58 .2977E-26 .3277E-26 −9.2 .0043 1 2460.19082 P56 .5294E-26 .4759E-26 11.2 .0091 1 2460.91043 P55 .5725E-26 .5702E-26 .4 .0130 1 2461.63782 P54 .5878E-26 .6806E-26 −13.6 .0185 1 2462.36011 P53 .8108E-26 .8092E-26 .2 .0262 1 2463.08082 P52 .9675E-26 .9584E-26 .9 .0367 1 2463.80064 P51 .1041E-25 .1131E-25 −8.0 .0511 1 2464.52377 P50 .1288E-25 .1329E-25 −3.1 .0706 1 2465.24313 P49 .1470E-25 .1655E-25 −5.5 .0967 1 2465.96435 P48 .2036E-25 .1813E-25 12.3 .1315 1 2466.68492 P47 .1873E-25 .2106E-25 −11.1 .1773 1 2467.40432 P46 .2278E-25 .2435E-25 −6.4 .2692 2 2468.12516 P45 .2761E-25 .2806E-25 −1.6 .3440 2 2468.84424 P44 .3175E-25 .3219E-25 −1.4 .4529 2 2469.66337 P43 .3717E-25 .3678E-25 1.1 .5914 2 2470.28285 P42 .4163E-25 .4186E-25 −.5 .7659 2 2471.00229 P41 .4714E-25 .4745E-25 −.7 .9839 2 2473.87949 P37 .7573E-25 .7510E-25 .8 1.2091 2 2474.59921 P36 .8611E-25 .8335E-25 3.3 1.2575 2 2477.47884 P32 .1254E-24 .1211E-24 3.6 1.5433 2 2478.19941 P31 .1332E-24 .1314E-24 1.4 1.6403 2 2478.92026 P30 .1404E-24 .1420E-24 −1.1 1.7477 2 2479.64129 P29 .1528E-24 .1528E-24 0.0 1.8651 2 2480.36260 P28 .1622E-24 .1636E-24 −.9 1.9915 2 2481.08449 P27 .1712E-24 .1743E-24 −1.8 2.0000 2 2482.52912 P25 .1961E-24 .1949E-24 .6 2.0000 2 2483.25183 P24 .2065E-24 .2045E-24 1.0 2.0000 2 2483.97515 P23 .2144E-24 .2135E-24 .4 2.0000 2 2484.69900 P22 .2251E-24 .2217E-24 1.5 2.0000 2 2485.42321 P21 .2301E-24 .2288E-24 .6 2.0000 2 2486.14786 P20 .2355E-24 .2349E-24 .3 2.0000 2 2486.87306 P19 .2388E-24 .2396E-24 −.3 2.0000 2 2487.59879 P18 .2429E-24 .2430E-24 −.0 2.0000 2 2488.32500 P17 .2458E-24 .2447E-24 .4 2.0000 2 2489.05172 P16 .2433E-24 .2447E-24 −.6 2.0000 2 2489.77917 P15 .2414E-24 .2429E-24 −.6 2.0000 2 2490.50692 P14 .2404E-24 .2392E-24 .5 2.0000 2 2491.23528 P13 .2319E-24 .2335E-24 −.7 2.0000 2 2491.96449 P12 .2225E-24 .2258E-24 −1.5 2.0000 2 2492.69401 P11 .2133E-24 .2160E-24 −1.3 2.0000 2 2493.42410 P10 .2088E-24 .2043E-24 2.2 2.0000 2 2494.15494 P 9 .1928E-24 .1906E-24 1.2 2.0000 2 2494.88640 P 8 .1696E-24 .1750E-24 −3.1 2.0000 2 2495.61861 P 7 .1619E-24 .1576E-24 −3.6 1.9200 2 2496.35121 P 6 .1368E-24 .1185E-24 −1.2 1.7108 2 2497.08446 P 5 .1172E-24 .1179E-24 −.6 1.5154 2 2497.81838 P 4 .9661E-25 .9607E-25 .6 1.3420 2 2498.55263 P 3 .7581E-25 .7310E-25 3.7 1.1981 2 2499.28739 P 2 .4899E-25 .4927E-25 −.6 1.0611 2 2500.02380 P 1 .2360E-25 .2482E-25 −4.9 .2692 2 2501.49701 R 0 .2545E-25 .2492E-25 2.1 .2715 2 2602.23433 R 1 .5128E-25 .4969E-25 3.2 1.0790 2 2502.97288 R 2 .7702E-25 .7403E-25 4.0 1.2031 2 2603.71145 R 3 .9992E-25 .9769E-25 2.3 1.3537 2 2504.45074 R 4 .1226E-24 .1204E-24 1.8 1.5375 2 2606.19091 R 5 .1471E-24 .1420E-24 3.6 1.7475 2 2505.93151 R 6 .1580E-24 .1622E-24 −2.6 1.9756 2 2506.67277 R 7 .1798E-24 .1809E-24 −.6 2.0000 2 2507.41436 R 8 .1932E-24 .1979E-24 −2.4 2.0000 2 2508.15659 R 9 .2137E-24 .2131E-24 .3 2.0000 2 2508.89928 R10 .2281E-24 .2261E-24 .8 2.0000 2 2609.64278 R11 .2379E-24 .2374E-24 .2 2.0000 2 2510.38649 R12 .2466E-24 .2466E-24 0.0 2.0000 2 2611.13078 R13 .2571E-24 .2537E-24 1.3 2.0000 2 2511.87569 R14 .2584E-24 .2587E-24 −.1 2.0000 2 2612.62088 R15 .2630E-24 .2617E-24 .5 2.0000 2 2513.36658 R16 .2627E-24 .2628E-24 −.0 2.0000 2 2614.11273 R17 .2634E-24 .2620E-24 .5 2.0000 2 2514.85927 R18 .2607E-24 .2595E-24 .5 2.0000 2 2515.60617 R19 .2574E-24 .2554E-24 .8 2.0000 2 2516.35343 R20 .2528E-24 .2499E-24 1.2 2.0000 2 2517.10092 R21 .2396E-24 .2431E-24 −1.4 2.0000 2 2517.84888 R22 .2338E-24 .2351E-24 −.6 2.0000 2 2518.59716 R23 .2244E-24 .2262E-24 −.8 2.0000 2 2519.34560 R24 .7138E-24 .2164E-24 −1.2 2.0000 2 2620.09430 R25 .2034E-24 .2060E-24 −1.3 2.0000 2 2520.84330 R26 .1956E-24 .1951E-24 .3 2.0000 2 2521.59236 R27 .1802E-24 .1839E-24 −2.0 2.0000 2 2522.34158 R28 .1697E-24 .1725E-24 −1.6 2.0000 2 2523.09091 R29 .1590E-24 .1611E-24 −1.3 1.9616 2 2523.84052 R30 .1451E-24 .1497E-24 −3.1 1.8304 2 2524.59004 R31 .1387E-24 .1385E-24 .1 1.7105 2 2525.33987 R32 .1290E-24 .1275E-24 1.2 1.6024 2 2626.08921 R33 .1187E-24 .1169E-24 1.5 1.5063 2 2526.83880 R34 .1052E-24 .1067E-24 −1.4 1.4217 2 2527.68827 R35 .9731E-25 .9693E-25 .4 1.3482 2 2528.33793 R36 .8940E-25 .8771E-25 1.9 1.2851 2 2529.08677 R37 .8009E-26 .7902E-25 1.4 1.2314 2 2529.83591 R38 .7056E-25 .7089E-25 −.5 1.1863 2 2630.58472 R39 .6439E-25 .6333E-25 1.7 1.1487 2 2531.33391 R40 .5659E-25 .5634E-25 .4 1.1177 2 2532.08193 R41 .4865E-25 .4992E-25 −2.5 1.0891 2 2532.82980 R42 .4300E-25 .4405E-25 −2.4 .8480 2 2633.57746 R43 .3717E-25 .3871E-25 −4.0 .6548 2 2535.07193 R45 .3195E-25 .2951E-25 8.2 .3811 2 2635.81807 R46 .2671E-25 .2564E-25 4.2 .2873 2 2536.56370 R47 .2015E-25 .2217E-25 −9.1 .1966 1 2638.79740 R50 .1591E-26 .1400E-25 13.6 .0784 1 2539.53947 R51 .1427E-25 .1192E-25 19.7 .0568 1 2540.28195 R52 .1250E-25 .1010E-25 23.8 .0408 1 2541.02357 R53 .9707E-26 .8633E-26 13.8 .0291 1 2541.76677 R54 .8282E-26 .7179E-26 15.4 .0206 1 2542.50567 R55 .5305E-26 .6016E-26 11.8 .0145 1 2643.74259 R56 .5197E-26 .5023E-26 3.5 .0101 1 2543.98464 R57 .5114E-26 .4177E-26 22.4 .0070 1 2644.71496 R58 .3750E-26 .3461E-26 8.4 .0048 1 2546.92117 R61 .2301E-26 .1923E-26 19.7 .0015 1 2547.65229 R62 .2489E-26 .1669E-26 58.6 .0010 1
(21102-01101) 628
OBSERVED POSITION LINE INTENSITY LINE OBS. CAL. β (%)W N 2583.07034 P47e .4046E-26 .1186E-26 241.1 .0006 1 2583.83989 P46e .3467E-26 .1374E-26 152.3 .0008 1 2585.53055 P45e .2828E-26 .1577E-26 79.3 .0010 1 2586.93714 P42e .2863E-26 .2375E-26 20.5 .0023 1 2588.45168 P41f .2176E-26 .2684E-26 −18.9 .0029 1 2588.48420 P40e .2748E-26 .3046E-26 −9.8 .0037 1 2589.25121 P39e .3162E-26 .3428E-26 −7.8 .0047 1 2589.91442 P39f .3760E-26 .3414E-26 10.1 .0047 1 2590.65579 P38f .3826E-26 .3827E-26 −.0 .0059 1 2590.78311 P37e .4414E-26 .4286E-26 3.0 .0073 1 2591.38714 P37f .5380E-26 .4271E-26 26.0 .0073 1 2591.55832 P36e .5062E-26 .4762E-26 6.3 .0091 1 2592.12308 P36f .6033E-26 .4747E-26 27.1 .0090 1 2592.32444 P35e .6166E-26 .5268E-26 17.0 .0111 1 2592.85568 P35e .5900E-26 .5252E-26 12.3 .0110 1 2593.08844 P34e .6590E-26 .5803E-26 13.6 .0135 1 2593.85492 P33e .6353E-26 .6363E-26 −.2 .0162 1 2594.32694 P33f .5788E-26 .6345E-26 −8.8 .0161 1 2594.61733 P32e .5843E-26 .6945E-26 −15.9 .0193 1 2595.06141 P32f .6026E-26 .6927E-26 −13.0 .0192 1 2595.38347 P31e .7735E-26 .7547E-26 2.5 .0228 1 2595.79764 P31f .8564E-26 .7528E-26 13.8 .0227 1 2596.14433 P30e .7590E-26 .8163E-26 −7.0 .0267 1 2596.53226 P30f .8552E-26 .8144E-26 5.0 .0265 1 2596.91196 P29e .1066E-2S .8788E-26 21.3 .0309 1 2597.26653 P29f .1050E-25 .8768E-26 19.8 .0308 1 2597.67123 P28e .8981E-26 .9415E-26 −4.6 .0355 1 2598.00173 P28f .1053E-25 .9396E-26 12.1 .0353 1 2598.42822 P27o .9055E-26 .1004E-25 −9.8 .0403 1 2598.73792 P27f .9249E-26 .1002E-25 −7.7 .0402 1 2599.18991 P26e .1053E-25 .1065E-25 −1.1 .0454 1 2599.47382 P26f .1026E-25 .1063E-25 −3.5 .0452 1 2599.94810 P25e .1049E-25 .1124E-25 −6.7 .0506 1 2600.20906 P25f .1122E-25 .1122E-25 0.0 .0504 1 2600.70767 P24e .1228E-25 .1181E-25 4.0 .0557 1 2600.94537 P24f .1133E-25 .1179E-25 −3.9 .0556 1 2601.46383 P23e .1169E-25 .1233E-25 −5.2 .0608 1 2601.68197 P23f .1240E-25 .1231E-25 .7 .0606 1 2602.22044 P22e .1335E-25 .1281E-25 4.2 .0656 1 2602.41909 P22f .1471E-25 .1279E-25 15.0 .0655 1 2602.97605 P21e .1137E-25 .1323E-25 −14.1 .0700 1 2603.15557 P21f .1392E-25 .1322E-25 5.3 .0699 1 2603.72997 P20e .1346E-25 .1359E-25 −1.0 .0738 1 2603.89227 P20f .1516E-25 .1357E-25 11.6 .0737 1 2604.48384 P19e .1270E-25 .1386E-25 −8.4 .0769 1 2605.23711 P18e .1508E-25 .1406E-25 7.3 .0791 1 2605.98945 P17e .1368E-25 .1416E-25 −3.4 .0802 1 2606.74231 P16e .1562E-2S .1416E-25 10.3 .0803 1 2607.49008 P15e .1281E-2S .1406E-25 −8.9 .0791 1 2608.24174 P14e .1269E-25 .1384E-25 −8.3 .0766 1 2609.73620 P12e .1363E-25 .1305E-25 4.4 .0681 1 2609.78881 P12f .1300E-2S .1305E-25 −.4 .0681 1 2610.48444 P11e .1190E-25 .1248E-25 −4.6 .0623 1 2610.52619 P11f .1130E-25 .1247E-25 −9.4 .0622 1 2611.23008 P10e .1171E-25 .1178E-25 −.6 .0555 1 2611.26416 P10f .1159E-25 .1178E-25 −1.6 .0555 1 2611.97750 P 9e .9940E-26 .1097E-25 −9.4 .0481 1 2612.00163 P 9f .1235E-25 .1096E-25 12.7 .0481 1 2623.04875 R 5e .7324E-26 .8048E-26 −9.0 .0259 1 2623.07380 R 5f .7280E-26 .8048E-26 −9.5 .0259 1 2623.77926 R 6e .1006E-25 .9262E-26 8.6 .0375 2 2623.81476 R 6f .9868E-26 .9261E-26 6.6 .0343 1 2624.50766 R 7e .1151E-25 .1038E-25 10.9 .0431 1 2624.54913 R 7f .1525E-25 .2038E-25 46.0 .0431 1 2625.23628 R 8e .1225E-25 .1138E-25 7.6 .0518 1 2625.29001 R 8f .1137E-25 .1138E-25 −.1 .0518 1 2625.96624 R 9e .1251E-25 .1228E-25 1.9 .0603 1 2626.02835 R 9f .1006E-25 .1228E-25 −18.1 .0603 1 2626.69341 R10e .1210E-25 .1306E-25 −7.4 .0682 1 2626.76783 R10f .1271E-25 .1306E-25 −2.7 .0682 1 2627.50565 R11e .1240E-25 .1371E-25 −9.6 .0752 1 2628.14420 R12e .1488E-25 .1425E-25 4.4 .0813 1 2628.24661 R12e .1319E-25 .1425E-25 −7.4 .0812 1 2628.86636 R13e .1406E-25 .1467E-25 −4.2 .0861 1 2629.59107 R14e .1627E-2S .1496E-25 8.8 .0895 1 2629.72194 R14f .1613E-25 .1495E-25 7.9 .0894 1 2630.31373 R15e .1578E-25 .1614E-25 4.2 .0916 1 2630.46030 R15f .1522E-25 .1513E-25 .6 .0915 1 2631.03493 R16e .1441E-25 .1520E-25 −5.2 .0924 1 2631.20018 R16f .1610E-25 .1519E-25 6.0 .0923 1 2631.75598 R17e .1595E-25 .1515E-25 5.3 .0918 1 2631.93987 R17f .1413E-25 .1514E-25 −6.7 .0917 1 2632.47427 R18e .1513E-25 .1500E-25 .9 .0900 1 2632.67884 R18e .1536E-25 .1499E-25 2.4 .0899 1 2633.19260 R19e .1384E-25 .1476E-25 −6.2 .0871 1 2633.41709 R19f .1581E-25 .1475E-25 7.2 .0870 1 2633.91085 R20e .1362E-25 .1443E-25 −5.6 .0833 1 2634.15522 R20f .1425E-25 .1442E-25 −1.2 .0832 1 2634.62820 R21e .1172E-25 .1403E-25 −16.5 .0788 1 2634.89611 R21f .1169E-25 .1402E-25 −16.6 .0786 1 2636.34231 R22e .1534E-25 .1356E-25 13.1 .0736 1 2635.63460 R22f .1330E-25 .1356E-25 −1.8 .0734 1 2636.05742 R23e .1232E-25 .1304E-25 −5.5 .0680 1 2636.37311 R23f .1480E-25 .1302E-25 13.7 .0678 1 2636.77131 R24e .1323E-25 .1247E-25 6.1 .0622 1 2637.11039 R24f .1338E-25 .1245E-25 7.5 .0620 1 2637.48332 R25e .1106E-25 .1186E-25 −6.7 .0563 1 2637.84975 R25f .1168E-25 .1184E-25 −1.4 .0561 1 2638.58903 R26f .1072E-25 .1121E-25 −4.4 .0502 1 2638.90697 R27e .1068E-25 .1057E-25 1.0 .0447 1 2639.32790 R27e .9100E-26 .1055E-25 −13.7 .0446 1 2639.61613 R28e .8248E-26 .9910E-26 −16.8 .0393 1 2640.06663 R28f .1049E-25 .9890E-26 6.1 .0391 1 2640.32464 R29e .9798E-26 .9243E-26 6.0 .0342 1 2640.80388 R29f .9060E-26 .9224E-26 −1.8 .0340 1 2641.03190 R30e .6768E-26 .8581E-26 −21.1 .0295 1 2641.54236 R30e .6566E-26 .8562E-26 −23.3 .0293 1 2641.73960 R31e .8811E-26 .7930E-26 11.1 .0252 1 2642.44559 R32e .8237E-26 .7295E-26 12.9 .0213 1 2643.02156 R32f .5555E-26 .7276E-26 −23.7 .0212 1 2643.15374 R33e .6428E-26 .6680E-26 −3.8 .0179 1 2643.76076 R33f .7065E-26 .6662E-26 6.0 .0178 1 2643.85139 R34e .7222E-26 .6090E-26 18.6 .0148 1 2644.55882 R35e .5902E-26 .5528E-26 6.8 .0122 1 2646.65850 R38e .2798E-26 .4029E-26 −30.6 .0065 1 2646.71491 R37f .5761E-26 .4480E-26 28.6 .0080 1 2647.36136 R39e .3611E-26 .3595E-26 .4 .0052 1 2647.45367 R38f .5433E-26 .4014E-26 35.4 .0064 1 2648.05235 R40e .4067E-26 .3194E-26 27.3 .0041 1 2648.19026 R39f .4139E-26 .3581E-26 15.6 .0051 1 2648.93708 R40e .2621E-26 .3181E-26 −17.6 .0040 1 2649.44744 R42e .1567E-26 .2490E-26 −37.1 .0025 1 2649.67066 R41f .1988E-26 .2814E-26 −29.4 .0032 1 2650.14331 R43e .1093E-26 .2185E-26 −50.0 .0019 1 2650.40950 R42e .2449E-26 .2479E-26 −1.2 .0025 1 2650.83460 R44e .3052E-26 .1910E-26 59.8 .0015 1 2651.88770 R44e .1381E-26 .1901E-26 −27.4 .0014 1 2652.62575 R45f .2138E-26 .1654E-26 29.3 .0012 2
(21103-01101) 628
OBSERVED POSITION LINE INTENSITY LINE OBS. CAL. β (%)W N 2432.55892 P44e .1145E-26 .1297E-26 −11.7 .0007 1 2434.03494 P42e .3431E-26 .1691E-26 102.9 .0011 1 2434.77314 P41e .3587E-26 .1919E-26 86.9 .0015 1 2436.24822 P39e .4373E-26 .2441E-26 79.1 .0024 1 2436.28454 P40f .1939E-26 .2160E-26 −10.2 .0019 1 2437.68913 P38f .1905E-26 .2725E-26 −30.1 .0030 1 2437.72963 P37e .2508E-26 .3052E-26 −17.8 .0037 1 2438.38542 P37f .2434E-26 .3041E-26 −20.0 .0037 1 2439.08551 P36f .3223E-26 .3380E-26 −4.6 .0046 1 2439.19904 P35e .4295E-26 .3751E-26 14.5 .0056 1 2439.94190 P34e .6927E-26 .4132E-26 67.6 .0068 1 2440.67380 P33e .3565E-26 .4531E-26 −21.3 .0082 1 2441.41264 P32e .3495E-26 .4946E-26 −29.3 .0098 1 2441.90159 P32f .4373E-26 .4933E-26 −11.4 .0097 1 2443.31395 P30f .5862E-26 .5799E-26 1.1 .0135 1 2443.62234 P29e .6584E-26 .6258E-26 5.2 .0157 1 2444.02241 P29f .7439E-26 .6244E-26 19.1 .0156 1 2444.35921 P28e .7899E-26 .6704E-26 17.8 .0180 1 2444.73129 P28f .6097E-26 .6691E-26 −8.9 .0179 1 2445.09681 P27e .7517E-26 .7148E-26 5.2 .0204 1 2445.83164 P26e .8339E-26 .7584E-26 10.0 .0230 1 2446.85928 P25f .7013E-26 .7993E-26 −12.3 .0256 1 2447.30495 P24e .7975E-26 .8407E-26 −5.1 .0283 1 2447.57160 P24f .8647E-26 .8394E-26 3.0 .0282 1 2448.03986 P23e .8630E-26 .8781E-26 −1.7 .0308 1 2448.77702 P22e .1005E-25 .9122E-26 10.2 .0333 1 2448.99905 P22f .9124E-26 .9110E-26 .2 .0332 1 2449.51306 P21e .1016E-25 .9422E-26 7.8 .0355 1 2449.71424 P21f .9342E-26 .9411E-26 −.7 .0354 1 2450.42931 P20f .9704E-26 .9665E-26 .4 .0374 1 2450.98363 P19e .1061E-25 .9874E-26 7.5 .0426 1 2451.14729 P19f .8853E-26 .9865E-26 −10.3 .0389 1 2451.72251 P18e .1143E-25 .1001E-25 14.2 .0401 1 2451.86453 P18f .9941E-26 .1001E-25 −.7 .0400 1 2452.58366 P17f .8611E-26 .1008E-25 −14.6 .0406 1 2453.19346 P16e .1090E-25 .1009E-25 8.0 .0407 1 2453.30349 P16f .8921E-26 .1008E-25 −11.5 .0406 1 2453.92990 P15e .9903E-26 .1001E-25 −1.1 .0401 1 2454.02542 P15f .1047E-25 .1001E-25 4.6 .0401 1 2454.66520 P14e .8828E-26 .9857E-26 −10.4 .0389 1 2454.74763 P14f .1071E-25 .9852E-26 8.7 .0388 1 2455.40276 P13e .8720E-26 .9619E-26 −9.3 .0370 1 2455.47247 P13f .8392E-26 .9615E-26 −12.7 .0370 1 2456.13910 P12e .1037E-25 .9296E-26 11.6 .0346 1 2456.19639 P12f .9387E-26 .9292E-26 1.0 .0345 1 2456.87569 P11e .8364E-26 .8887E-26 −5.9 .0316 1 2457.61149 P10e .7046E-26 .8391E-26 −16.0 .0282 1 2457.64953 P10f .9685E-26 .8389E-26 15.4 .0281 1 2458.34946 P 9e .8417E-26 .7811E-26 7.8 .0244 1 2458.37711 P 9f .7687E-26 .7810E-26 −1.6 .0244 1 2469.40422 R 5e .6161E-26 .5734E-26 7.4 .0131 1 2469.43427 R 5f .6428E-26 .5733E-26 12.1 .0131 1 2470.14100 R 6e .5883E-26 .6599E-26 −10.9 .0174 1 2470.18259 R 6f .6225E-26 .6598E-26 −5.7 .0174 1 2470.87957 R 7e .5641E-26 .7393E-26 −23.7 .0219 1 2470.92729 R 7f .6242E-26 .7392E-26 −15.6 .0219 1 2471.61876 R 8e .7362E-26 .8111E-26 −9.2 .0263 1 2471.67427 R 8f .7159E-26 .8109E-26 −11.7 .0263 1 2473.09344 R10e .9469E-26 .9305E-26 1.8 .0346 1 2473.83124 R11e .9965E-26 .9774E-26 2.0 .0382 1 2473.92781 R11f .8785E-26 .9771E-26 −10.1 .0382 1 2474.68175 R12f .1076E-25 .1015E-25 6.0 .0412 1 2475.43459 R13f .8960E-26 .1045E-25 −14.3 .0437 1 2476.18729 R14f .1072E-25 .1066E-2S .6 .0454 1 2476.94314 R15f .1166E-25 .1078E-25 8.2 .0466 1 2477.51795 R16e .1137E-2S .1083E-25 5.0 .0469 1 2477.70164 R16f .1118E-25 .1082E-25 3.3 .0468 1 2478.25488 R17e .1114E-25 .1080E-25 3.1 .0466 1 2478.99327 R18e .9661E-26 .1069E-25 −9.6 .0457 1 2479.21773 R18f .1097E-25 .1068E-25 2.7 .0456 1 2479.72924 R19e .9848E-26 .1052E-25 −6.4 .0443 1 2479.97562 R19f .1185E-25 .1051E-25 12.7 .0442 1 2480.46551 R20e .8039E-26 .1029E-25 −21.9 .0423 1 2481.20392 R21e .9276E-26 .1000E-25 −7.2 .0400 1 2481.49697 R21f .8054E-26 .9989E-26 −19.4 .0399 1 2481.94017 R22e .1085E-25 .9667E-26 12.2 .0374 1 2482.26150 R22f .9315E-26 .9655E-26 −3.5 .0373 1 2482.67730 R23e .9748E-26 .9294E-26 4.9 .0346 1 2483.02291 R23f .8100E-26 .9281E-26 −12.7 .0345 1 2483.41463 R24e .1064E-25 .8887E-26 19.7 .0316 1 2483.78707 R24f .7999E-26 .8875E-26 −9.9 .0315 1 2484.14995 R2Se .9166E-26 .8455E-26 8.4 .0286 1 2484.55129 R25f .8180E-26 .8441E-26 −3.1 .0285 1 2484.88512 R26e .8257E-26 .8002E-26 3.2 .0256 1 2485.31435 R26f .9085E-26 .7989E-26 13.7 .0255 1 2485.62106 R27e .8118E-26 .7537E-26 7.7 .0227 1 2486.08189 R27f .7614E-26 .7523E-26 1.2 .0226 1 2486.35700 R28e .1057E-25 .7064E-26 49.6 .0200 1 2487.09162 R29e .6536E-26 .6589E-26 −.8 .0174 1 2488.38386 R30f .7012E-26 .6103E-26 14.9 .0149 1 2488.55910 R31e .6674E-26 .5653E-26 18.1 .0128 1 2489.15467 R31f .4606E-26 .5639E-26 −18.3 .0127 1 2489.29640 R32e .5727E-26 .5200E-26 10.1 .0108 1 2489.92134 R32f .5231E-26 .5187E-26 .8 .0108 1 2490.03118 R33e .4755E-26 .4762E-26 −.1 .0091 1 2490.69346 R33f .4362E-26 .4750E-26 −8.2 .0090 1 2490.76328 R34e .3400E-26 .4342E-26 −21.7 .0075 1 2491.46223 R34f .4791E-26 .4329E-26 10.7 .00/5 1 2491.49579 R35e .3968E-26 .3942E-26 .7 .0062 1 2492.95879 R37e .2826E-26 .3206E-26 −11.9 .0041 1 2493.00581 R36f .3879E-26 .3551E-26 9.2 .0050 1 2493.69445 R38e .2313E-26 .2872E-26 −19.5 .0033 1 2493.77979 R37f .3069E-26 .3195E-26 −3.9 .0041 1 2494.42698 R39e .1383E-26 .2563E-26 −46.0 .0026 1 2494.55475 R38f .3075E-26 .2862E-26 7.4 .0033 1 2495.15181 R40e .2586E-26 .2277E-26 13.6 .0021 1 2495.32362 R39f .4676E-26 .2553E-26 83.2 .0026 1 2496.09800 R40f .3221E-26 .2268E-26 42.0 .0021 1 2496.61623 R42e .1836E-26 .1776E-26 3.4 .0013 1 2497.34725 R43e .2533E-26 .1558E-26 62.6 .0010 1 2497.64835 R42f .1993E-26 .1768E-26 12.7 .0013 1 2498.07319 R44e .1784E-26 .1362E-26 28.3 .0007 1
(20002-00001) 628
OBSERVED POSITION LINE INTENSITY LINE OBS. CAL. β (%)W N 2565.63599 P64 .2650E-26 .1409E-26 88.1 .0008 1 2566.41314 P63 .2743E-26 .1749E-26 56.8 .0012 1 2567.95909 P61 .2468E-26 .2661E-26 −7.3 .0028 1 2568.74015 P60 .1246E-26 .3264E-26 −61.8 .0043 1 2569.51149 P59 .3296E-26 .3988E-26 −17.4 .0064 1 2570.28357 P58 .4951E-26 .4854E-26 2.0 .0094 1 2571.06314 P57 .6033E-26 .5884E-26 2.5 .0138 1 2571.83273 P56 .8276E-26 .7105E-26 16.5 .0202 1 2572.60742 P55 .9153E-26 .8546E-26 7.1 .0292 1 2573.37920 P54 .1157E-2S .1024E-25 13.0 .0419 1 2574.15144 P53 .1486E-25 .1222E-25 21.6 .0597 1 2574.92475 P52 .1247E-25 .1452E-25 −14.1 .0843 1 2575.69666 P51 .1549E-25 .1719E-25 −9.9 .1181 1 2576.46822 P50 .1924E-25 .2028E-25 −5.1 .1643 1 2577.23959 P49 .2435E-25 .2382E-25 2.2 .2477 2 2578.00955 P48 .2718E-25 .2786E-25 −2.4 .3389 2 2579.55027 P46 .3853E-25 .3766E-25 2.3 .6196 2 2580.31933 P45 .4447E-25 .4353E-25 2.2 .8273 2 2581.08866 P44 .5118E-25 .5009E-25 2.2 1.0929 2 2581.85731 P43 .5773E-25 .5741E-25 .6 1.1221 2 2582.62503 P42 .6676E-25 .6553E-25 1.9 1.1591 2 2583.39225 P41 .7562E-26 .7449E-25 1.5 1.2055 2 2584.15904 P40 .8612E-25 .8431E-25 2.1 1.2633 2 2584.92504 P39 .9765E-25 .9503E-25 2.8 1.3345 2 2585.69092 P38 .1123E-24 .1067E-24 5.2 1.4213 2 2586.45574 P37 .1191E-24 .1192E-24 −.1 1.5261 2 2587.22012 P36 .1340E-24 .1326E-24 1.1 1.6514 2 2587.98389 P35 .1480E-24 .1469E-24 .7 1.7993 2 2588.74700 P34 .1607E-24 .1620E-24 −.8 1.9722 2 2589.50967 P33 .1758E-24 .1779E-24 −1.2 2.0000 2 2590.27138 P32 .1914E-24 .1944E-24 −1.5 2.0000 2 2591.03250 P31 .2103E-24 .2116E-24 −.6 2.0000 2 2591.79307 P30 .2249E-24 .2290E-24 −1.8 2.0000 2 2592.55271 P29 .2446E-24 .2469E-24 −.9 2.0000 2 2593.31184 P28 .2647E-24 .2648E-24 −.0 2.0000 2 2594.07018 P27 .2792E-24 .2826E-24 −1.2 2.0000 2 2594.82781 P26 .3002E-24 .3002E-24 0.0 2.0000 2 2595.58469 P25 .3122E-24 .3172E-24 −1.6 2.0000 2 2596.34086 P24 .3294E-24 .3334E-24 −1.2 2.0000 2 2597.09632 P23 .3471E-24 .3486E-24 −.4 2.0000 2 2597.85095 P22 .3596E-24 .3625E-24 −.8 2.0000 2 2598.60483 P21 .3723E-24 .3748E-24 −.7 2.0000 2 2599.35795 P20 .3801E-24 .3852E-24 −1.3 2.0000 2 2600.11030 P19 .3998E-24 .3935E-24 1.6 2.0000 2 2601.61252 P17 .4039E-24 .4028E-24 .3 2.0000 2 2602.36249 P16 .4060E-24 .4033E-24 .7 2.0000 2 2603.11165 P15 .4008E-24 .4007E-24 .0 2.0000 2 2603.85995 P14 .3919E-24 .3949E-24 −.8 2.0000 2 2608.33233 P 8 .2886E-24 .2902E-24 −.6 2.0000 2 2609.81637 P 6 .2282E-24 .2299E-24 −.7 2.0000 2 2610.55716 P 5 .1900E-24 .1958E-24 −3.0 2.0000 2 2611.29699 P 4 .1600E-24 .1596E-24 .3 1.9436 2 2612.03615 P 3 .1210E-24 .1214E-24 −.3 1.5466 2 2612.77417 P 2 .8191E-25 .8186E-25 .1 1.2484 2 2613.51115 P 1 .4355E-25 .4124E-25 5.6 .7433 2 2615.71739 R 1 .8958E-25 .8254E-25 8.5 1.2525 2 2616.45292 R 2 .1217E-24 .1229E-24 −1.0 1.0000 1 2617.18413 R 3 .1743E-24 .1622E-24 7.5 1.9750 2 2617.91632 R 4 .2004E-24 .1999E-24 .3 2.0000 2 2618.64732 R 5 .2435E-24 .2356E-24 3.4 2.0000 2 2619.37750 R 6 .2687E-24 .2690E-24 −.1 1.0000 1 2620.10684 R 7 .3088E-24 .2998E-24 3.0 1.0000 1 2620.83528 R 8 .3376E-24 .3278E-24 3.0 1.0000 1 2621.56255 R 9 .3575E-24 .3526E-24 1.4 2.0000 2 2622.28915 R10 .3724E-24 .3741E-24 −.5 2.0000 2 2623.01476 R11 .3897E-24 .3923E-24 −.7 2.0000 2 2623.73966 R12 .4030E-24 .4070E-24 −1.0 2.0000 2 2624.46347 R13 .4116E-24 .4183E-24 −1.6 2.0000 2 2626.18638 R14 .4206E-24 .4261E-24 −1.3 2.0000 2 2625.90846 R15 .4260E-24 .4306E-24 −1.1 2.0000 2 2626.62961 R16 .4320E-24 .4319E-24 .0 2.0000 2 2627.34992 R17 .4305E-24 .4301E-24 .1 2.0000 2 2628.06935 R18 .4261E-24 .4254E-24 .2 2.0000 2 2628.78779 R19 .4142E-24 .4182E-24 −1.0 2.0000 2 2629.50543 R20 .4075E-24 .4085E-24 −.2 2.0000 2 2630.22202 R21 .3948E-24 .3967E-24 −.5 2.0000 2 2630.93794 R22 .3774E-24 .3831E-24 −1.5 2.0000 2 2631.65284 R23 .3619E-24 .3679E-24 −1.6 2.0000 2 2632.36693 R24 .3492E-24 .3514E-24 −.6 2.0000 2 2633.08017 R25 .3282E-24 .3339E-24 −1.7 2.0000 2 2633.79241 R26 .3096E-24 .3157E-24 −1.9 2.0000 2 2634.50372 R27 .2894E-24 .2970E-24 −2.6 2.0000 2 2635.21437 R28 .2688E-24 .2780E-24 −3.3 2.0000 2 2636.63299 R30 .2344E-24 .2401E-24 −2.4 2.0000 2 2639.45997 R34 .1715E-24 .1695E-24 1.2 2.0000 2 2640.16458 R3S .1590E-24 .1537E-24 3.4 1.8748 2 2640.86839 R36 .1440E-24 .1387E-24 3.8 1.7125 2 2641.57114 R37 .1250E-24 .1246E-24 .3 1.5762 2 2642.97476 R39 .9723E-25 .9932E-25 −2.1 1.3654 2 2643.67525 R40 .8570E-25 .8811E-25 −2.7 1.2875 2 2644.37535 R41 .7832E-26 .7783E-25 .6 1.0000 1 2645.07433 R42 .6962E-25 .6847E-25 1.7 1.1736 2 2646.47020 R44 .5254E-25 .5233E-25 .4 1.1014 2 2647.16724 R45 .4564E-25 .4547E-25 .4 .9028 2 2647.86306 R46 .3898E-25 .3935E-25 −.9 .6760 2 2648.55820 R47 .3435E-25 .3391E-25 1.3 .5071 2 2649.25264 R48 .2836E-25 .2911E-25 −2.6 .3699 2 2649.94725 R49 .2376E-25 .2488E-25 −4.5 .2703 2 2650.64086 R50 .2131E-25 .2119E-25 .6 .1960 2 2651.33366 R51 .1678E-25 .1797E-25 −6.6 .1290 1 2652.02613 R52 .1449E-25 .1518E-25 −4.5 .0920 1 2652.71614 R53 .1084E-25 .1277E-25 −15.1 .0652 1 2653.40685 R54 .1057E-25 .1070E-25 −1.2 .0458 1 2654.09743 R55 .7708E-26 .8934E-26 −13.7 .0319 1 2654.78568 R56 .7411E-26 .7429E-26 −.2 .0220 1 2656.85336 R59 .5270E-26 .4172E-26 26.3 .0070 1 2657.53799 R60 .4068E-26 .3416E-26 19.1 .0051 2 2658.22142 R61 .3074E-26 .2785E-26 10.4 .0031 1 2659.59873 R63 .3038E-26 .1831E-26 65.9 .0013 1
Observed line positions are in cm
−1 .
Molecule codes: 626 =
12 C
16 O
2 , 628 =
16 O
12 C
18 O, 627 =
16 O
12 C
17 O, and 638 =
16 O
13 C
18 O.
Table III
Vibrational Band Intensity S v , F -Factor Coefficients, and Integrated Intensity S band Determined from the Analysis
Vibrational transition Moleculea S v b a 1 (in 10−2 )a 2 (in 10−4 )S band b 20011 ← 20002 626 0.085(8) 0.085 10011 ← 10002 626 66.35(18) −0.165(5) −0.167(14) 65.26 20012 ← 20003 626 0.137(8) 0.137 11111 ← 11102 626 1.59(1) −0.247(17) 1.59 20003 ← 00001 628 13.91(4) 0.069(18) 11.49 20002 ← 00001 628 23.11(8) −0.103(17) 25.13 21102 ← 01101 628 1.62(2) 1.62 10011 ← 10002 628 0.325(11) 0.325 21103 ← 01101 628 1.15(1) 1.15 20002 ← 00001 627 1.14(1) 1.14 20003 ← 00001 627 0.507(12) 0.507 20002 ← 00001 638 0.242(14) 0.242
a Molecule codes: 626 =
12 C
16 O
2 , 628 =
16 O
12 C
18 O, 627 =
16 O
12 C
17 O, 638 =
16 O
13 C
18 O.
b Values for
S v and
S band are in units of 10
−24 cm
−1 /molecule cm
−2 at 296 K obtained with CO
2 in natural abundance. Values in parentheses are standard deviations in units of last digit.
Table IV
Comparison of Integrated Intensities (in 10−24 cm−1 /molecule cm−2 at 296 K) Reported for CO2 Bands in the 2395–2680-cm−1 Region
Integrated intensity
Moleculea Vibrational transition Present study 1982 AFGL b Hoke and Shawc Plyler et al .d 1982 AFGL b /present study 626 20011 ← 20002 0.085 0.146 1.72 626 10011 ← 10002 65.26 105.90 69 1.62 626 20012 ← 20003 0.137 0.256 1.87 626 11111 ← 11102 1.59 40.20 25.3 628 20003 ← 00001 11.49 7.50 0.65 628 20002 ← 00001 25.13 18.60 21.80 0.74 628 21102 ← 01101 1.62 1.48 1.13 0.91 628 10011 ← 10002 0.325 0.56 1.72 628 21103 ← 01101 1.15 0.58 0.50 627 20002 ← 00001 1.14 1.80 1.33 1.57 627 20003 ← 00001 0.507 0.60 1.18 638 20002 ← 00001 0.242 0.20 0.83
a Molecule codes: 626 =
12 C
16 O
2 , 628 =
16 O
12 C
18 O, 627 =
16 O
12 C
17 O, 638 =
16 O
13 C
18 O.
b Air Force Geophysics Laboratory (AFGL) line compilation values.
10
c From Ref.
13 .
d From Ref.
14 .